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Heterogeneous Gold‐Catalysed Synthesis of Phenols
Abstract
Nanoparticles of gold supported on nanocrystalline CeO 2 catalyse the isomerisation of ω‐alkynylfurans to phenols. Initial leaching of gold was observed, which could be minimised by calcining. Subsequent runs showed that once all soluble species had leached, the surface‐bound, cationic gold species is still active and can reach turnover numbers of up to 391. This is the first time that a heterogeneous gold catalyst showed activity in the gold‐catalysed phenol synthesis.
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Citations
Cited by
Hashmi, A. S. K., & Hutchings, G. J. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602454 · Cited by 3,423
Self-citationSupported gold nanoparticles as catalysts for organic reactions
Corma, A., & Garcia, H. (2008) · Chemical Society Reviews · doi:10.1039/b707314n · Cited by 1,883
Self-citationCatalysis by Supported Gold Nanoparticles: Beyond Aerobic Oxidative Processes
Stratakis, M., & Garcia, H. (2012) · Chemical Reviews · doi:10.1021/cr3000785 · Cited by 803
Identification of single-site gold catalysis in acetylene hydrochlorination
Malta, G., Kondrat, S. A., Freakley, S. J., Davies, C. J., Lu, L., Dawson, S., Thetford, A., Gibson, E. K., Morgan, D. J., Jones, W., et al. (2017) · Science · doi:10.1126/science.aal3439 · Cited by 513
Metadata
- Authors
- Carrettin, S., Blanco, M. C., Corma, A., & Hashmi, A. S. K.
- Venue
- Advanced Synthesis & Catalysis
- Publisher
- Wiley
- Published
- 2006-07
- Volume
- 348
- Issue
- 10-11
- Pages
- 1283-1288
- ISSN
- 1615-4150 (ISSN-L)
- 1615-4169
- OpenAlex
- W2090974694
- Cited by
- 221
- References
- 0
- FWCI
- 7.38
- Type
- journal article
- Language
- en
- Open access
- closed
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- Carrettin, S., Blanco, M. C., Corma, A., & Hashmi, A. S. K. (2006). Heterogeneous Gold‐Catalysed Synthesis of Phenols. Advanced Synthesis & Catalysis. https://doi.org/10.1002/adsc.200606099
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