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Supported Ultra Small Palladium on Magnetic Nanoparticles Used as Catalysts for Suzuki Cross‐Coupling and Heck Reactions
Abstract
Application of transition metal nanoparticles as catalysts for organic transformations has been attracting wide interest as nanoparticle‐based catalytic systems might exhibit superior catalytic activities than the corresponding bulk materials. However, the main difficulty is that such small particles are almost impossible to separate by conventional means, which can lead to the blocking of filters and valves by the nanoparticle catalyst. We have conveniently prepared ultra small palladium(0) particles (less than 1 nm) on magnetic nanoparticle supports, in which immobilized auxiliaries are used as stabilizing ligands. These catalysts were active for Suzuki cross‐coupling and Heck reactions giving isolated yields of 83 % and 56 %, respectively. In addition, the catalyst can be easily separated using a magnet and reused several times with sustained activity.
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Cites
Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices
Sun, S., Murray, C. B., Weller, D., Folks, L., & Moser, A. (2000) · Science · doi:10.1126/science.287.5460.1989 · Cited by 6,137
Narayanan, R., & El-Sayed, M. A. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp051066p · Cited by 1,298
Cited by
Efficient, Selective, and Recyclable Palladium Catalysts in Carbon−Carbon Coupling Reactions
Molnár, Á. (2011) · Chemical Reviews · doi:10.1021/cr100355b · Cited by 1,042
Sustainable Preparation of Supported Metal Nanoparticles and Their Applications in Catalysis
Campelo, J. M., Luna, D., Luque, R., Marinas, J. M., & Romero, A. A. (2009) · ChemSusChem · doi:10.1002/cssc.200800227 · Cited by 800
Sharma, R. K., Yadav, P., Yadav, M., Gupta, R., Rana, P., Srivastava, A., Zbořil, R., Varma, R. S., Antonietti, M., & Gawande, M. B. (2020) · Materials Horizons · doi:10.1039/c9mh00856j · Cited by 455
Magnetic Nanocomposites: A New Perspective in Catalysis
Zhu, Y., Stubbs, L. P., Ho, F., Liu, R., Ship, C. P., Maguire, J. A., & Hosmane, N. S. (2010) · ChemCatChem · doi:10.1002/cctc.200900314 · Cited by 417
Metadata
- Authors
- Yinghuai, Z., Peng, S. C., Emi, A., Zhenshun, S., Monalisa, & Kemp, R. A.
- Venue
- Advanced Synthesis & Catalysis
- Publisher
- Wiley
- Published
- 2007-08-06
- Volume
- 349
- Issue
- 11-12
- Pages
- 1917-1922
- ISSN
- 1615-4150 (ISSN-L)
- 1615-4169
- OpenAlex
- W2095629709
- Cited by
- 167
- References
- 2
- FWCI
- 5.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Yinghuai, Z., Peng, S. C., Emi, A., Zhenshun, S., Monalisa, & Kemp, R. A. (2007). Supported Ultra Small Palladium on Magnetic Nanoparticles Used as Catalysts for Suzuki Cross‐Coupling and Heck Reactions. Advanced Synthesis & Catalysis. https://doi.org/10.1002/adsc.200700021
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