The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
Efficient and Reabsorption‐Free Radioluminescence in Cs3Cu2I5 Nanocrystals with Self‐Trapped Excitons
Open accessAbstract
Radioluminescent materials (scintillators) are widely applied in medical imaging, nondestructive testing, security inspection, nuclear and radiation industries, and scientific research. Recently, all‐inorganic lead halide perovskite nanocrystal (NC) scintillators have attracted great attention due to their facile solution processability and ultrasensitive X‐ray detection, which allows for large area and flexible X‐ray imaging. However, the light yield of these perovskite NCs is relatively low because of the strong self‐absorption that reduces the light out‐coupling efficiency. Here, NCs with self‐trapped excitons emission are demonstrated to be sensitive, reabsorption‐free scintillators. Highly luminescent and stable Cs 3 Cu 2 I 5 NCs with a photoluminescence quantum yields of 73.7%, which is a new record for blue emission lead‐free perovskite or perovskite‐like NCs, is produced with the assistance of InI 3. The PL peak of the Cs 3 Cu 2 I 5 NCs locates at 445 nm that matches with the response peak of a silicon photomultiplier. Thus, Cs 3 Cu 2 I 5 NCs are demonstrated as efficient scintillators with zero self‐absorption and extremely high light yield (≈79 279 photons per MeV). Both Cs 3 Cu 2 I 5 NC colloidal solution and film exhibit strong radioluminescence under X‐ray irradiation. The potential application of Cs 3 Cu 2 I 5 NCs as reabsorption‐free, low cost, large area, and flexible scintillators is demonstrated by a prototype X‐ray imaging with a high spatial resolution.
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Lead‐Free Highly Efficient Blue‐Emitting Cs3Cu2I5 with 0D Electronic Structure
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Cited by
Metal Halide Perovskites for X-ray Imaging Scintillators and Detectors
Zhou, Y., Chen, J., Bakr, O. M., & Mohammed, O. F. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.0c02430 · Cited by 891
Perovskite: Scintillators, direct detectors, and X-ray imagers
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Ma, W., Jiang, T., Yang, Z., Zhang, H., Su, Y., Chen, Z., Chen, X., Ma, Y., Zhu, W., Yu, X., et al. (2021) · Advanced Science · doi:10.1002/advs.202003728 · Cited by 322
Mn2+‐Doped Metal Halide Perovskites: Structure, Photoluminescence, and Application
Su, B., Zhou, G., Huang, J., Song, E., Nag, A., & Xia, Z. (2021) · Laser & Photonics Reviews · doi:10.1002/lpor.202000334 · Cited by 319
Metadata
- Authors
- Lian, L., Zheng, M., Zhang, W., Yin, L., Du, X., Zhang, P., Zhang, X., Gao, J., Zhang, D., Gao, L., Niu, G., Song, H., Chen, R., Lan, X., Tang, J., & Zhang, J.
- Venue
- Advanced Science
- Publisher
- Wiley
- Published
- 2020-04-16
- Volume
- 7
- Issue
- 11
- Pages
- 2000195-2000195
- ISSN
- 2198-3844 (ISSN-L)
- OpenAlex
- W3016293489
- Cited by
- 489
- References
- 43
- FWCI
- 45.25
- Type
- journal article
- Language
- en
- Open access
- gold
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- Lian, L., Zheng, M., Zhang, W., Yin, L., Du, X., Zhang, P., Zhang, X., Gao, J., Zhang, D., Gao, L., Niu, G., Song, H., Chen, R., Lan, X., Tang, J., & Zhang, J. (2020). Efficient and Reabsorption‐Free Radioluminescence in Cs3Cu2I5 Nanocrystals with Self‐Trapped Excitons. Advanced Science. https://doi.org/10.1002/advs.202000195
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