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Electrochemical Performance of Porous Carbon/Tin Composite Anodes for Sodium‐Ion and Lithium‐Ion Batteries
Abstract
The electrochemical performance of mesoporous carbon (C)/tin (Sn) anodes in Na‐ion and Li‐ion batteries is systematically investigated. The mesoporous C/Sn anodes in a Na‐ion battery shows similar cycling stability but lower capacity and poorer rate capability than that in a Li‐ion battery. The desodiation potentials of Sn anodes are approximately 0.21 V lower than delithiation potentials. The low capacity and poor rate capability of C/Sn anode in Na‐ion batteries is mainly due to the large Na‐ion size, resulting in slow Na‐ion diffusion and large volume change of porous C/Sn composite anode during alloy/dealloy reactions. Understanding of the reaction mechanism between Sn and Na ions will provide insight towards exploring and designing new alloy‐based anode materials for Na‐ion batteries.
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Cited by
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Pan, H., Hu, Y.-S., & Chen, L. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40847g · Cited by 3,319
An, S. J., Li, J., Daniel, C., Mohanty, D., Nagpure, S., & Wood, D. L. (2016) · Carbon · doi:10.1016/j.carbon.2016.04.008 · Cited by 2,121
Update on Na-based battery materials. A growing research path
Palomares, V., Casas-Cabanas, M., Castillo-Martínez, E., Han, M. H., & Rojo, T. (2013) · Energy & Environmental Science · doi:10.1039/c3ee41031e · Cited by 992
Shell Thickness-Dependent Microwave Absorption of Core–Shell Fe3O4@C Composites
Du, Y., Liu, W., Qiang, R., Wang, Y., Han, X., Ma, J., & Xu, P. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am502910d · Cited by 990
Sodium Metal Anodes: Emerging Solutions to Dendrite Growth
Lee, B., Paek, E., Mitlin, D., & Lee, S. W. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00642 · Cited by 940
Metadata
- Authors
- Xu, Y., Zhu, Y., Liu, Y., & Wang, C.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2012-09-03
- Volume
- 3
- Issue
- 1
- Pages
- 128-133
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2136363517
- Cited by
- 847
- References
- 0
- FWCI
- 36.02
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xu, Y., Zhu, Y., Liu, Y., & Wang, C. (2013). Electrochemical Performance of Porous Carbon/Tin Composite Anodes for Sodium‐Ion and Lithium‐Ion Batteries. Advanced Energy Materials. https://doi.org/10.1002/aenm.201200346
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