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Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room‐Temperature Sodium‐Ion Batteries
Abstract
A Na3V2(PO4)3/C composite with 3.8 wt.% carbon, which was synthesized by a one-step solid state reaction, exhibits Na storage capacity of 107 mAh g−1 and high coulombic efficiency of 99.8% in a new NaFSI/PC electrolyte. In situ XRD results reveal its sodium storage mechanism as a typical two-phase reaction from the Na3V2(PO4)3 to NaV2(PO4)3 phases with 8.26% volume variation. These desired properties make it very promising for application in room-temperature sodium- ion batteries.
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Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Cited by
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Zuo, W., Li, R., Zhou, C., Li, Y., Xia, J., & Liu, J. (2017) · Advanced Science · doi:10.1002/advs.201600539 · Cited by 1,637
Update on Na-based battery materials. A growing research path
Palomares, V., Casas-Cabanas, M., Castillo-Martínez, E., Han, M. H., & Rojo, T. (2013) · Energy & Environmental Science · doi:10.1039/c3ee41031e · Cited by 992
An Amorphous Red Phosphorus/Carbon Composite as a Promising Anode Material for Sodium Ion Batteries
Kim, Y., Park, Y., Choi, A., Choi, N., Kim, J., Lee, J., Ryu, J. H., Oh, S. M., & Lee, K. T. (2013) · Advanced Materials · doi:10.1002/adma.201204877 · Cited by 854
Towards polyvalent ion batteries: A zinc-ion battery based on NASICON structured Na3V2(PO4)3
Li, G., Yang, Z., Jiang, Y., Jin, C., Huang, W., Ding, X., & Huang, Y. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.051 · Cited by 734
A zero-strain layered metal oxide as the negative electrode for long-life sodium-ion batteries
Wang, Y., Yu, X., Xu, S., Bai, J., Xiao, R., Hu, Y.-S., Li, H., Yang, X.-Q., Chen, L., & Huang, X. (2013) · Nature Communications · doi:10.1038/ncomms3365 · Cited by 616
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Metadata
- Authors
- Jian, Z., Han, W., Lu, X., Yang, H., Hu, Y., Zhou, J., Zhou, Z., Li, J., Chen, W., Chen, D., & Chen, L.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2012-10-23
- Volume
- 3
- Issue
- 2
- Pages
- 156-160
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2006471296
- Cited by
- 970
- References
- 1
- FWCI
- 33.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jian, Z., Han, W., Lu, X., Yang, H., Hu, Y., Zhou, J., Zhou, Z., Li, J., Chen, W., Chen, D., & Chen, L. (2013). Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room‐Temperature Sodium‐Ion Batteries. Advanced Energy Materials. https://doi.org/10.1002/aenm.201200558
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