The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Toward an Active and Stable Catalyst for Oxygen Evolution in Acidic Media: Ti‐Stabilized MnO2
Abstract
Catalysts are required for the oxygen evolution reaction, which are abundant, active, and stable in acid. MnO 2 is a promising candidate material for this purpose. However, it dissolves at high overpotentials. Using first‐principles calculations, a strategy to mitigate this problem by decorating undercoordinated surface sites of MnO 2 with a stable oxide is developed here. TiO 2 stands out as the most promising of the different oxides in the simulations. This prediction is experimentally verified by testing sputter‐deposited thin films of MnO 2 and Ti–MnO 2. A combination of electrochemical measurements, quartz crystal microbalance, inductively coupled plasma mass spectrometry measurements, and X‐ray photoelectron spectroscopy is performed. Small amounts of TiO 2 incorporated into MnO 2 lead to a moderate improvement in stability, with only a small decrease in activity. This study opens up the possibility of engineering surface properties of catalysts so that active and abundant nonprecious metal oxides can be used in acid electrolytes.
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Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
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Self-citationUniversality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Self-citationPhotocatalytic Water Splitting: Recent Progress and Future Challenges
Maeda, K., & Domen, K. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1007966 · Cited by 2,739
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Anion-exchange membranes in electrochemical energy systems
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Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction
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Cited by
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Self-citationA review on fundamentals for designing oxygen evolution electrocatalysts
Song, J., Wei, C., Huang, Z.-F., Liu, C., Zeng, L., Wang, X., & Xu, Z. J. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00607a · Cited by 2,936
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Chen, F.-Y., Wu, Z.-Y., Adler, Z., & Wang, H. (2021) · Joule · doi:10.1016/j.joule.2021.05.005 · Cited by 1,284
Reier, T., Nong, H. N., Teschner, D., Schlögl, R., & Strasser, P. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601275 · Cited by 1,253
Metadata
- Authors
- Frydendal, R., Paoli, E. A., Chorkendorff, I., Rossmeisl, J., & Stephens, I. E. L.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2015-08-07
- Volume
- 5
- Issue
- 22
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2099073690
- Cited by
- 228
- References
- 8
- FWCI
- 5.57
- Type
- journal article
- Language
- en
- Open access
- closed
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- Frydendal, R., Paoli, E. A., Chorkendorff, I., Rossmeisl, J., & Stephens, I. E. L. (2015). Toward an Active and Stable Catalyst for Oxygen Evolution in Acidic Media: Ti‐Stabilized MnO2. Advanced Energy Materials. https://doi.org/10.1002/aenm.201500991
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