The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Observation of Pseudocapacitive Effect and Fast Ion Diffusion in Bimetallic Sulfides as an Advanced Sodium‐Ion Battery Anode
Abstract
Sodium‐ion batteries (SIBs) are promising next‐generation alternatives due to the low cost and abundance of sodium sources. Yet developmental electrodes in SIBs such as transition metal sulfides have huge volume expansion, sluggish Na+ diffusion kinetics, and poor electrical conductivity. Here bimetallic sulfide (Co 9 S 8/ZnS) nanocrystals embedded in hollow nitrogen‐doped carbon nanosheets are demonstrated with a high sodium diffusion coefficient, pseudocapacitive effect, and excellent reversibility. Such a unique composite structure is designed and synthesized via a facile sulfidation of the CoZn‐MOFs followed by calcination and is highly dependant on the reaction time and temperature. The optimized Co 1 Zn 1‐S(600) electrode exhibits excellent sodium storage performance, including a high capacity of 542 mA h g−1 at 0.1 A g−1, good rate capability at 10 A g−1, and excellent cyclic stability up to 500 cycles for half‐cell. It also shows potential in full‐cell configuration. Such capabilities will accelerate the adoption of sodium‐ion batteries for electrical energy applications.
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Cites
Huang, Z.-F., Song, J., Li, K., Tahir, M., Wang, Y.-T., Pan, L., Wang, L., Zhang, X., & Zou, J.-J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b11986 · Cited by 749
Cited by
Chandrasekaran, S., Yao, L., Deng, L., Bowen, C., Zhang, Y., Chen, S., Lin, Z., Peng, F., & Zhang, P. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00664d · Cited by 1,199
Fang, G., Wang, Q., Zhou, J., Lei, Y., Chen, Z., Wang, Z., Pan, A., & Liang, S. (2019) · ACS Nano · doi:10.1021/acsnano.9b00816 · Cited by 507
Self-citationRational Design of MOF-Based Materials for Next-Generation Rechargeable Batteries
Ye, Z., Jiang, Y., Li, L., Wu, F., & Chen, R. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00726-z · Cited by 323
Luo, J., Zheng, J., Nai, J., Jin, C., Yuan, H., Sheng, O., Liu, Y., Fang, R., Zhang, W., Huang, H., et al. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201808107 · Cited by 292
Wu, Z., Xie, J., Xu, Z. J., Zhang, S., & Zhang, Q. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta11994e · Cited by 292
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Metadata
- Authors
- Fang, G., Wu, Z., Zhou, J., Zhu, C., Cao, X., Lin, T., Chen, Y., Wang, C., Pan, A., & Liang, S.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2018-03-27
- Volume
- 8
- Issue
- 19
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2794560912
- Cited by
- 525
- References
- 1
- FWCI
- 28.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- Fang, G., Wu, Z., Zhou, J., Zhu, C., Cao, X., Lin, T., Chen, Y., Wang, C., Pan, A., & Liang, S. (2018). Observation of Pseudocapacitive Effect and Fast Ion Diffusion in Bimetallic Sulfides as an Advanced Sodium‐Ion Battery Anode. Advanced Energy Materials. https://doi.org/10.1002/aenm.201703155
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