The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Tuning Electronic Structure of NiFe Layered Double Hydroxides with Vanadium Doping toward High Efficient Electrocatalytic Water Oxidation
Abstract
Binary NiFe layer double hydroxide (LDH) serves as a benchmark non‐noble metal electrocatalyst for the oxygen evolution reaction, however, it still needs a relatively high overpotential to achieve the threshold current density. Herein the catalyst's electronic structure is tuned by doping vanadium ions into the NiFe LDHs laminate forming ternary NiFeV LDHs to reduce the onset potential, achieving unprecedentedly efficient electrocatalysis for water oxidation. Only 1.42 V (vs reversible hydrogen electrode (RHE), ≈195 mV overpotential) is required to achieve catalytic current density of 20 mA cm−2 with a small Tafel slope of 42 mV dec−1 in 1 m KOH solution, which manifests the best of NiFe‐based catalysts reported till now. Electrochemical analysis and density functional theory +U simulation indicate that the high catalytic activity of NiFeV LDHs mainly attributes to the vanadium doping which can modify the electronic structure and narrow the bandgap thereby bring enhanced conductivity, facile electron transfer, and abundant active sites.
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Cites
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J., & Grätzel, M. (2014) · Science · doi:10.1126/science.1258307 · Cited by 2,509
Wang, H., Lee, H.-W., Deng, Y., Lu, Z., Hsu, P.-C., Liu, Y., Lin, D., & Cui, Y. (2015) · Nature Communications · doi:10.1038/ncomms8261 · Cited by 1,257
Jia, X., Zhao, Y., Chen, G., Shang, L., Shi, R., Kang, X., Waterhouse, G. I. N., Wu, L., Tung, C., & Zhang, T. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201502585 · Cited by 773
Cited by
Li, P., Wang, M., Duan, X., Zheng, L., Cheng, X., Zhang, Y., Kuang, Y., Li, Y., Ma, Q., Feng, Z., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-09666-0 · Cited by 717
Self-citationYan, H., Xie, Y., Wu, A., Cai, Z., Wang, L., Tian, C., Zhang, X., & Fu, H. (2019) · Advanced Materials · doi:10.1002/adma.201901174 · Cited by 640
Stability of electrocatalytic OER: from principle to application
Li, H., Lin, Y., Duan, J., Wen, Q., Liu, Y., & Zhai, T. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00010a · Cited by 540
Hu, X., Zhang, S., Sun, J., Yu, L., Qian, X., Hu, R., Wang, Y., Zhao, H., & Zhu, J. (2019) · Nano Energy · doi:10.1016/j.nanoen.2018.11.047 · Cited by 268
Ir–O–V Catalytic Group in Ir-Doped NiV(OH)2 for Overall Water Splitting
Li, S., Xi, C., Jin, Y.-Z., Wu, D., Wang, J.-Q., Liu, T., Wang, H.-B., Dong, C.-K., Liu, H., Kulinich, S. A., et al. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b01252 · Cited by 182
Metadata
- Authors
- Li, P., Duan, X., Kuang, Y., Li, Y., Zhang, G., Liu, W., & Sun, X.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2018-02-12
- Volume
- 8
- Issue
- 15
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2792655791
- Cited by
- 757
- References
- 4
- FWCI
- 20.25
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, P., Duan, X., Kuang, Y., Li, Y., Zhang, G., Liu, W., & Sun, X. (2018). Tuning Electronic Structure of NiFe Layered Double Hydroxides with Vanadium Doping toward High Efficient Electrocatalytic Water Oxidation. Advanced Energy Materials. https://doi.org/10.1002/aenm.201703341
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