The DOI matches its Crossref record; 40 of the 40 references it cites were found in a registry or an index.
Alkali Chlorides for the Suppression of the Interfacial Recombination in Inverted Planar Perovskite Solar Cells
Abstract
In this work, significant suppression of the interfacial recombination by facile alkali chloride interface modification of the NiOx hole transport layer in inverted planar perovskite solar cells is achieved. Experimental and theoretical results reveal that the alkali chloride interface modification results in improved ordering of the perovskite films, which in turn reduces defect/trap density, causing reduced interfacial recombination. This leads to a significant improvement in the open‐circuit voltage from 1.07 eV for pristine NiOx to 1.15 eV for KCl‐treated NiOx, resulting in a power conversion efficiency approaching 21%. Furthermore, the suppression of the ion diffusion in the devices is observed, as evidenced by stable photoluminescence (PL) under illumination and high PL quantum efficiency with alkali chloride treatment, as opposed to the luminescence enhancement and low PL quantum efficiency observed for perovskite on pristine NiOx. The suppressed ion diffusion is also consistent with improved stability of the devices with KCl‐treated NiOx. Thus, it is demonstrated that a simple interfacial modification is an effective method to not only suppress interfacial recombination but also to suppress ion migration in the layers deposited on the modified interface due to improved interface ordering and reduced defect density.
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Cites
Efficient and stable solution-processed planar perovskite solar cells via contact passivation
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Self-citationPromises and challenges of perovskite solar cells
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Challenges for commercializing perovskite solar cells
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Maximizing and stabilizing luminescence from halide perovskites with potassium passivation
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Formamidinium and Cesium Hybridization for Photo‐ and Moisture‐Stable Perovskite Solar Cell
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Enhanced photovoltage for inverted planar heterojunction perovskite solar cells
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Defects in perovskite-halides and their effects in solar cells
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Cited by
Reducing Surface Halide Deficiency for Efficient and Stable Iodide-Based Perovskite Solar Cells
Wu, W.-Q., Rudd, P. N., Ni, Z., Van Brackle, C. H., Wei, H., Wang, Q., Ecker, B. R., Gao, Y., & Huang, J. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b13418 · Cited by 341
Kim, S., Jang, J. H., Wu, Z., Lee, M. J., Woo, H. Y., & Hwang, I. (2021) · Small · doi:10.1002/smll.202101839 · Cited by 36
Metadata
- Authors
- Chen, W., Zhou, Y., Chen, G., Wu, Y., Tu, B., Liu, F., Huang, L., Ng, A. M. C., Djurišić, A. B., & He, Z.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2019-03-25
- Volume
- 9
- Issue
- 19
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2943382880
- Cited by
- 348
- References
- 40
- FWCI
- 17.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, W., Zhou, Y., Chen, G., Wu, Y., Tu, B., Liu, F., Huang, L., Ng, A. M. C., Djurišić, A. B., & He, Z. (2019). Alkali Chlorides for the Suppression of the Interfacial Recombination in Inverted Planar Perovskite Solar Cells. Advanced Energy Materials. https://doi.org/10.1002/aenm.201803872
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