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Boronization-induced ultrathin 2D nanosheets with abundant crystalline-amorphous phase boundary supported on nickel foam toward efficient water splitting
Abstract
The conversion of crystalline metal–organic frameworks (MOFs) into metal compounds/carbon hybrid nanocomposites via pyrolysis provides a promising solution to design electrocatalysts for electrochemical water splitting. However, pyrolyzing MOFs generally involves a complex high‐temperature treatment, which can destroy the coordinated surroundings within MOFs, and as a result not taking their full advantage of their electrolysis properties. Herein, a simple and room‐temperature boronization strategy is developed to convert nickel zeolite imidazolate framework (Ni‐ZIF) nanorods into ultrathin Ni‐ZIF/NiB nanosheets with abundant crystalline–amorphous phase boundaries. The combined experiment, and theoretical calculation results disclose that the ultrathin thickness allows fast electron transfer and ensures increased exposure of surface coordinatively unsaturated active sites while the crystalline–amorphous interface elaborately changes the potential‐determining step to energetically favorable intermediates. As a result, Ni‐ZIF/NiB nanosheets supported on nickel foam (NF) require overpotentials of 67 mV for the hydrogen evolution reaction and 234 mV for the oxygen evolution reaction to achieve a current density of 10 mA cm −2 . Remarkably, Ni‐ZIF/NiB@NF as a bifunctional electrocatalyst for overall water splitting enables an alkaline electrolyzer with 10 mA cm −2 at an ultralow cell voltage of 1.54 V. The present work may open a new avenue to the design of MOF‐derived composit…
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“As predicted, this would offer more active sites for OER and HER catalyses [31,32].”
From Wood aerogel-derived sandwich-like layered nanoelectrodes for alkaline overall seawater electrosplitting (2021) · cites this paper as [32]
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Metadata
- Authors
- Xu, H., Fei, B., Cai, G., Ha, Y., Liu, J., Jia, H., Zhang, J., Liu, M., & Wu, R.
- Affiliations
- Fudan University (CN)
- Chinese Academy of Sciences (CN)
- Corresponding author
- Wu, Renbing
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2019-11-22
- Volume
- 10
- Issue
- 3
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2990016020
- Cited by
- 332
- References
- 42
- Citations by year
- 2026: 12 · 2025: 38 · 2024: 67 · 2023: 50 · 2022: 77 · 2021: 61 · 2020: 27
- FWCI
- 8.78
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Energy Materials (publishedVersion)
- Funders
- National Natural Science Foundation of China (51672049, 51871060, 51831009, 11705270)
- CURE Childhood Cancer
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Aqueous and Flow Batteries
- Keywords
- boronization, metal-organic frameworks, amorphous-crystalline interface, ultrathin nanosheets, nickel foam, hydrogen evolution reaction, oxygen evolution reaction, bifunctional electrocatalysts, overall water splitting, alkaline electrolyzer, pyrolysis, potential-determining step
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