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Cited by 423

The DOI matches its Crossref record; 127 of the 127 references it cites were found in a registry or an index.

Atomic‐Level Reactive Sites for Semiconductor‐Based Photocatalytic CO2 Reduction

Zhang, Yanzhao, Xia, Bingquan, Ran, Jingrun, Davey, Kenneth, Qiao, Shi Zhang·2020·Advanced Energy Materials

Abstract

Photocatalytic CO 2 reduction is an effective means to generate renewable energy. It involves redox reactions, reduction of CO 2 and oxidation of water, that leads to the production of solar fuel. Significant research effort has therefore been made to develop inexpensive and practically sustainable semiconductor‐based photocatalysts. The exploration of atomic‐level active sites on the surface of semiconductors can result in an improved understanding of the mechanism of CO 2 photoreduction. This can be applied to the design and synthesis of efficient photocatalysts. In this review, atomic‐level reactive sites are classified into four types: vacancies, single atoms, surface functional groups, and frustrated Lewis pairs (FLPs). These different photocatalytic reactive sites are shown to have varied affinity to reactants, intermediates, and products. This changes pathways for CO 2 reduction and significantly impacts catalytic activity and selectivity. The design of a photocatalyst from an atomic‐level perspective can therefore be used to maximize atomic utilization efficiency and lead to a high selectivity. The prospects for fabrication of effective photocatalysts based on an in‐depth understanding are highlighted.

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Metadata

Authors
Zhang, Y., Xia, B., Ran, J., Davey, K., & Qiao, S. Z.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2020-01-31
Volume
10
Issue
9
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W3003267829
Cited by
423
References
127
FWCI
14.17
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Atomic‐Level Reactive Sites for Semiconductor‐Based Photocatalytic CO2 Reduction. https://app.cochat.ai/papers/10.1002/aenm.201903879
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Zhang, Y., Xia, B., Ran, J., Davey, K., & Qiao, S. Z. (2020). Atomic‐Level Reactive Sites for Semiconductor‐Based Photocatalytic CO2 Reduction. Advanced Energy Materials. https://doi.org/10.1002/aenm.201903879

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