The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Tailoring Selectivity of Electrochemical Hydrogen Peroxide Generation by Tunable Pyrrolic‐Nitrogen‐Carbon
Abstract
The electrochemical reduction of O 2 via a two‐electron reaction pathway to H 2 O 2 provides a possibility for replacing the current anthraquinone process, enabling sustainable and decentralized H 2 O 2 production. Here, a nitrogen‐rich few‐layered graphene (N‐FLG) with a tunable nitrogen configuration is developed for electrochemical H 2 O 2 generation. A positive correlation between the content of pyrrolic‐N and the H 2 O 2 selectivity is experimentally observed. The critical role of pyrrolic‐N is elucidated by the variable intermediate adsorption profiles as well as the dependent negative shifts of the pyrrolic‐N peak on X‐ray adsorption near edge structure spectra. By virtue of the optimized N doping configuration and the unique porous structure, the as‐fabricated N‐FLG electrocatalyst exhibits high selectivity toward electrochemical H 2 O 2 synthesis as well as superior long‐term stability. To achieve high‐value products on both the anode and cathode with optimized energy efficiency, a practical device coupling electrochemical H 2 O 2 generation and furfural oxidation is assembled, simultaneously enabling a high yield rate of H 2 O 2 at the cathode (9.66 mol h−1 g cat−1) and 2‐furoic acid at the anode (2.076 mol m−2 h−1) under a small cell voltage of 1.8 V.
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Cites
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
Self-citationJiao, Y., Zheng, Y., Davey, K., & Qiao, S.-Z. (2016) · Nature Energy · doi:10.1038/nenergy.2016.130 · Cited by 1,196
Self-citationTuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst
Choi, C. H., Kim, M., Kwon, H. C., Cho, S. J., Yun, S., Kim, H.-T., Mayrhofer, K. J. J., Kim, H., & Choi, M. (2016) · Nature Communications · doi:10.1038/ncomms10922 · Cited by 849
Cited by
Chen, S., Luo, T., Li, X., Chen, K., Fu, J., Liu, K., Cai, C., Wang, Q., Li, H., Chen, Y., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c01194 · Cited by 560
Zhang, C., Shen, W., Guo, K., Xiong, M., Zhang, J., & Lu, X. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c00689 · Cited by 363
Dong, K., Liang, J., Wang, Y., Xu, Z., Liu, Q., Luo, Y., Li, T., Li, L., Shi, X., Asiri, A. M., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202101880 · Cited by 339
Self-citationPeng, W., Liu, J., Liu, X., Wang, L., Yin, L., Tan, H., Hou, F., & Liang, J. (2023) · Nature Communications · doi:10.1038/s41467-023-40118-y · Cited by 312
Zhao, Q., Wang, Y., Lai, W.-H., Xiao, F., Lyu, Y., Liao, C., & Shao, M. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00878a · Cited by 269
Metadata
- Authors
- Li, L., Tang, C., Zheng, Y., Xia, B., Zhou, X., Xu, H., & Qiao, S.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2020-04-17
- Volume
- 10
- Issue
- 21
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W3017316500
- Cited by
- 479
- References
- 4
- FWCI
- 13.11
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, L., Tang, C., Zheng, Y., Xia, B., Zhou, X., Xu, H., & Qiao, S. (2020). Tailoring Selectivity of Electrochemical Hydrogen Peroxide Generation by Tunable Pyrrolic‐Nitrogen‐Carbon. Advanced Energy Materials. https://doi.org/10.1002/aenm.202000789
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