The DOI matches its Crossref record; 50 of the 50 references it cites were found in a registry or an index.
Phase Behavior during Electrochemical Cycling of Ni‐Rich Cathode Materials for Li‐Ion Batteries
Open accessAbstract
Although layered lithium nickel‐rich oxides have become the state‐of‐the‐art cathode materials for lithium‐ion batteries in electric vehicle (EV) applications, they can suffer from rapid performance failure—particularly when operated under conditions of stress (temperature, high voltage)‐the underlying mechanisms of which are not fully understood. This essay aims to connect electrochemical performance with changes in structure during cycling. First, structural properties of LiNiO 2 are compared to the substituted Ni‐rich compounds NMCs (LiNixMnyCo 1−x−yO 2) and NCAs (LiNixCoyAl 1−x−yO 2). Particular emphasis is placed on decoupling intrinsic behavior and extrinsic “two‐phase” reactions observed during initial cycles, as well as after extensive cycling for NMC and NCA cathodes. The need to revisit the various high‐voltage structural changes that occur in LiNiO 2 with modern characterization tools is highlighted to aid the understanding of the accelerated degradation for Ni‐rich cathodes at high voltages.
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Cites
Lithium Batteries and Cathode Materials
Whittingham, M. S. (2004) · Chemical Reviews · doi:10.1021/cr020731c · Cited by 6,267
Performance and cost of materials for lithium-based rechargeable automotive batteries
Schmuch, R., Wagner, R., Hörpel, G., Placke, T., & Winter, M. (2018) · Nature Energy · doi:10.1038/s41560-018-0107-2 · Cited by 3,233
Batteries and fuel cells for emerging electric vehicle markets
Cano, Z. P., Banham, D., Ye, S., Hintennach, A., Lu, J., Fowler, M., & Chen, Z. (2018) · Nature Energy · doi:10.1038/s41560-018-0108-1 · Cited by 2,873
Noh, H.-J., Youn, S., Yoon, C. S., & Sun, Y.-K. (2013) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.01.063 · Cited by 2,302
The development and future of lithium ion batteries
Blomgren, G. E. (2017) · Journal of The Electrochemical Society · doi:10.1149/2.0251701jes · Cited by 1,940
Structural classification and properties of the layered oxides
Delmas, C., Fouassier, C., & Hagenmuller, P. (1980) · Physica B+C · doi:10.1016/0378-4363(80)90214-4 · Cited by 1,783
High-nickel layered oxide cathodes for lithium-based automotive batteries
Li, W., Erickson, E. M., & Manthiram, A. (2020) · Nature Energy · doi:10.1038/s41560-019-0513-0 · Cited by 1,754
Lin, F., Markus, I. M., Nordlund, D., Weng, T.-C., Asta, M. D., Xin, H. L., & Doeff, M. M. (2014) · Nature Communications · doi:10.1038/ncomms4529 · Cited by 1,481
Manganese oxides for lithium batteries
Thackeray, M. M. (1997) · Progress in Solid State Chemistry · doi:10.1016/s0079-6786(97)81003-5 · Cited by 1,475
Electrochemistry and Structural Chemistry of LiNiO2 (R3m) for 4 Volt Secondary Lithium Cells
Ohzuku, T., Ueda, A., & Nagayama, M. (1993) · Journal of The Electrochemical Society · doi:10.1149/1.2220730 · Cited by 1,384
Cited by
Building Practical High‐Voltage Cathode Materials for Lithium‐Ion Batteries
Xiang, J., Wei, Y., Zhong, Y., Yang, Y., Cheng, H., Yuan, L., Xu, H., & Huang, Y. (2022) · Advanced Materials · doi:10.1002/adma.202200912 · Cited by 394
Wang, J., Li, D., Zeng, W., Chen, X., Zhang, Y., Zhang, S., Li, Z., Li, C., & Mu, S. (2025) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2024.11.016 · Cited by 62
Battery State of Health Estimate Strategies: From Data Analysis to End-Cloud Collaborative Framework
Yang, K., Zhang, L., Zhang, Z., Yu, H., Wang, W., Ouyang, M., Zhang, C., Sun, Q., Yan, X., Yang, S., et al. (2023) · Batteries · doi:10.3390/batteries9070351 · Cited by 58
Kunz, A., Kirst, C., Durdel, A., Singer, J. P., & Jossen, A. (2025) · Journal of Power Sources · doi:10.1016/j.jpowsour.2024.235732 · Cited by 6
Metadata
- Authors
- Xu, C., Reeves, P. J., Jacquet, Q., & Grey, C. P.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2020-12-21
- Volume
- 11
- Issue
- 7
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W3112750320
- Cited by
- 429
- References
- 50
- FWCI
- 13.42
- Type
- journal article
- Language
- en
- Open access
- green
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- Xu, C., Reeves, P. J., Jacquet, Q., & Grey, C. P. (2021). Phase Behavior during Electrochemical Cycling of Ni‐Rich Cathode Materials for Li‐Ion Batteries. Advanced Energy Materials. https://doi.org/10.1002/aenm.202003404
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