The DOI matches its Crossref record; 69 of the 69 references it cites were found in a registry or an index.
Fe Single‐Atom Catalysts on MOF‐5 Derived Carbon for Efficient Oxygen Reduction Reaction in Proton Exchange Membrane Fuel Cells
Abstract
The development of Fe single‐atom catalysts (Fe SACs) with abundant, accessible Fe sites is a key step toward enhancing the efficiency of the oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). In this study, Zn 4 O(1,4‐benzenedicarboxylate)3 (MOF‐5), which has a 3D microporous cubic structure, is used as the precursor to prepare highly‐porous carbon (denoted as C‐MOF‐5) with an ultrahigh specific surface area (2751 m 2 g–1) and high external surface area (1651 m 2 g–1). C‐MOF‐5 is demonstrated as an effective carbon support to yield Fe SAC‐MOF‐5 with a large amount of accessible FeNx sites (2.35 wt%). Fe SAC‐MOF‐5 delivers a half‐wave potential of 0.83 V (vs RHE) in a 0.5 m H 2 SO 4 electrolyte, and achieves a peak power density of 0.84 W cm–2 in a 0.2 MPa H 2‐O 2 PEMFC. This excellent performance originates from the ultrahigh specific surface area of C‐MOF‐5 for the formation of a high density of single Fe atoms, and high external surface area for the increased exposure of active sites. This work may inspire the rational design of metal single‐atom catalysts derived from a wider range of MOF precursors with ultrahigh specific area to improve the performance of the oxygen reduction reaction in PEMFCs.
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Cites
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Li, H., Eddaoudi, M., O'Keeffe, M., & Yaghi, O. M. (1999) · Nature · doi:10.1038/46248 · Cited by 8,554
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells
Lefèvre, M., Proietti, E., Jaouen, F., & Dodelet, J.-P. (2009) · Science · doi:10.1126/science.1170051 · Cited by 3,139
Chen, Y., Ji, S., Wang, Y., Dong, J., Chen, W., Li, Z., Shen, R., Zheng, L., Zhuang, Z., Wang, D., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201702473 · Cited by 1,988
Fei, H., Dong, J., Feng, Y., Allen, C. S., Wan, C., Volosskiy, B., Li, M., Zhao, Z., Wang, Y., Sun, H., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0008-y · Cited by 1,973
Metal-Organic Framework as a Template for Porous Carbon Synthesis
Liu, B., Shioyama, H., Akita, T., & Xu, Q. (2008) · Journal of the American Chemical Society · doi:10.1021/ja7106146 · Cited by 1,829
Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
Chung, H. T., Cullen, D. A., Higgins, D., Sneed, B. T., Holby, E. F., More, K. L., & Zelenay, P. (2017) · Science · doi:10.1126/science.aan2255 · Cited by 1,684
Kaye, S. S., Dailly, A., Yaghi, O. M., & Long, J. R. (2007) · Journal of the American Chemical Society · doi:10.1021/ja076877g · Cited by 1,660
Atomically dispersed Fe 3+ sites catalyze efficient CO 2 electroreduction to CO
Gu, J., Hsu, C.-S., Bai, L., Chen, H. M., & Hu, X. (2019) · Science · doi:10.1126/science.aaw7515 · Cited by 1,610
Wang, J., Huang, Z., Liu, W., Chang, C., Tang, H., Li, Z., Chen, W., Jia, C., Yao, T., Wei, S., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10385 · Cited by 1,596
Zhang, H., Hwang, S., Wang, M., Feng, Z., Karakalos, S., Luo, L., Qiao, Z., Xie, X., Wang, C., Su, D., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b06514 · Cited by 1,526
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Cited by
Self-supporting metal–organic framework-based hydrogen and oxygen electrocatalysts
Sun, X., Wang, S., Hou, Y., Lu, X. F., Zhang, J., & Wang, X. (2023) · Journal of Materials Chemistry A · doi:10.1039/d3ta01903a · Cited by 97
Metadata
- Authors
- Xie, X., Shang, L., Xiong, X., Shi, R., & Zhang, T.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2021-12-15
- Volume
- 12
- Issue
- 3
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W4200194813
- Cited by
- 291
- References
- 69
- FWCI
- 9.87
- Type
- journal article
- Language
- en
- Open access
- closed
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