The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
High‐Entropy and Superstructure‐Stabilized Layered Oxide Cathodes for Sodium‐Ion Batteries
Open accessAbstract
Layered transition metal oxides are appealing cathodes for sodium‐ion batteries due to their overall advantages in energy density and cost. But their stabilities are usually compromised by the complicated phase transition and the oxygen redox, particularly when operating at high voltages, leading to poor structural stability and substantial capacity loss. Here an integrated strategy combing the high‐entropy design with the superlattice‐stabilization to extend the cycle life and enhance the rate capability of layered cathodes is reported. It is shown that the as‐prepared high‐entropy Na 2/3 Li 1/6 Fe 1/6 Co 1/6 Ni 1/6 Mn 1/3 O 2 cathode enables a superlattice structure with Li/transition metal ordering and delivers excellent electrochemical performance that is not affected by the presence of phase transition and oxygen redox. It achieves a high reversible capacity (171.2 mAh g−1 at 0.1 C), a high energy density (531 Wh kg−1), extended cycling stability (89.3% capacity retention at 1 C for 90 cycles and 63.7% capacity retention at 5 C after 300 cycles), and excellent fast‐charging capability (78 mAh g−1 at 10 C). This strategy would inspire more rational designs that can be leveraged to improve the reliability of layered cathodes for secondary‐ion batteries.
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Rost, C. M., Sachet, E., Borman, T., Moballegh, A., Dickey, E. C., Hou, D., Jones, J. L., Curtarolo, S., & Maria, J.-P. (2015) · Nature Communications · doi:10.1038/ncomms9485 · Cited by 3,525
A cost and resource analysis of sodium-ion batteries
Vaalma, C., Buchholz, D., Weil, M., & Passerini, S. (2018) · Nature Reviews Materials · doi:10.1038/natrevmats.2018.13 · Cited by 2,613
Structural classification and properties of the layered oxides
Delmas, C., Fouassier, C., & Hagenmuller, P. (1980) · Physica B+C · doi:10.1016/0378-4363(80)90214-4 · Cited by 1,783
Seo, D.-H., Lee, J., Urban, A., Malik, R., Kang, S., & Ceder, G. (2016) · Nature Chemistry · doi:10.1038/nchem.2524 · Cited by 1,561
Rational design of layered oxide materials for sodium-ion batteries
Zhao, C., Wang, Q., Yao, Z., Wang, J., Sánchez-Lengeling, B., Ding, F., Qi, X., Lu, Y., Bai, X., Li, B., et al. (2020) · Science · doi:10.1126/science.aay9972 · Cited by 1,540
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes
Sathiya, M., Rousse, G., Ramesha, K., Laisa, C. P., Vezin, H., Sougrati, M. T., Doublet, M.-L., Foix, D., Gonbeau, D., Walker, W., et al. (2013) · Nature Materials · doi:10.1038/nmat3699 · Cited by 1,539
Layered Oxide Cathodes for Sodium‐Ion Batteries: Phase Transition, Air Stability, and Performance
Wang, P., You, Y., Yin, Y., & Guo, Y. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201701912 · Cited by 994
Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes
House, R. A., Maitra, U., Pérez-Osorio, M. A., Lozano, J. G., Jin, L., Somerville, J. W., Duda, L. C., Nag, A., Walters, A., Zhou, K.-J., et al. (2020) · Nature · doi:10.1038/s41586-019-1854-3 · Cited by 848
High‐Entropy Layered Oxide Cathodes for Sodium‐Ion Batteries
Zhao, C., Ding, F., Lu, Y., Chen, L., & Hu, Y. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201912171 · Cited by 771
House, R. A., Rees, G. J., Pérez-Osorio, M. A., Marie, J.-J., Boivin, E., Robertson, A. W., Nag, A., Garcia-Fernandez, M., Zhou, K.-J., & Bruce, P. G. (2020) · Nature Energy · doi:10.1038/s41560-020-00697-2 · Cited by 558
Cited by
Ding, F., Ji, P., Han, Z., Hou, X., Yang, Y., Hu, Z., Niu, Y., Liu, Y., Zhang, J., Rong, X., et al. (2024) · Nature Energy · doi:10.1038/s41560-024-01616-5 · Cited by 280
The promise of high-entropy materials for high-performance rechargeable Li-ion and Na-ion batteries
Zheng, W., Liang, G., Liu, Q., Li, J., Yuwono, J. A., Zhang, S., Peterson, V. K., & Guo, Z. (2023) · Joule · doi:10.1016/j.joule.2023.10.016 · Cited by 279
Metadata
- Authors
- Yao, L., Zou, P., Wang, C., Jiang, J., Ma, L., Tan, S., Beyer, K. A., Xu, F., Hu, E., & Xin, H. L.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2022-09-08
- Volume
- 12
- Issue
- 41
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W4294982883
- Cited by
- 280
- References
- 17
- FWCI
- 14.79
- Type
- journal article
- Language
- en
- Open access
- green
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- Yao, L., Zou, P., Wang, C., Jiang, J., Ma, L., Tan, S., Beyer, K. A., Xu, F., Hu, E., & Xin, H. L. (2022). High‐Entropy and Superstructure‐Stabilized Layered Oxide Cathodes for Sodium‐Ion Batteries. Advanced Energy Materials. https://doi.org/10.1002/aenm.202201989
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