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Multicomponent adsorption equilibria of nonideal mixtures
Abstract
Experimental gas‐solid adsorption measurements were made on the binary and ternary mixtures of H 2 S, CO 2, and C 3 H 8 on H‐mordenite molecular sieve zeolite at 30°C. The C 3 H 8 containing binaries and the ternary mixture exhibited nonideal behavior, as evidenced by the azeotropelike crossovers in the composition domains and by the peaks in the total amount adsorbed surface. The ternary data were successfully predicted with the activity coefficients calculated by the spreading‐pressure‐dependent equation. Models that neglect the spreading‐pressure dependence can only qualitatively predict the nonidealities.
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Cited by
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Sircar, S. (2006) · Industrial & Engineering Chemistry Research · doi:10.1021/ie051056a · Cited by 324
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Simon, C. M., Smit, B., & Haranczyk, M. (2016) · Computer Physics Communications · doi:10.1016/j.cpc.2015.11.016 · Cited by 304
(2003) · doi:10.1201/9780203911167.ch22 · Cited by 39
Net adsorption of gas/vapor mixtures in microporous solids
Talu, O. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp4021382 · Cited by 33
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Metadata
- Authors
- Talu, O., & Zwiebel, I.
- Venue
- AIChE Journal
- Publisher
- Wiley
- Published
- 1986-08
- Volume
- 32
- Issue
- 8
- Pages
- 1263-1276
- ISSN
- 0001-1541 (ISSN-L)
- 1547-5905
- OpenAlex
- W2136492756
- Cited by
- 277
- References
- 0
- FWCI
- 3.05
- Type
- journal article
- Language
- en
- Open access
- closed
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- Talu, O., & Zwiebel, I. (1986). Multicomponent adsorption equilibria of nonideal mixtures. AIChE Journal. https://doi.org/10.1002/aic.690320805
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