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Methane steam reforming, methanation and water‐gas shift: I. Intrinsic kinetics
Abstract
Intrinsic rate equations were derived for the steam reforming of methane, accompanied by water‐gas shift on a Ni/MgAl 2 O 4 catalyst. A large number of detailed reaction mechanisms were considered. Thermodynamic analysis helped in reducing the number of possible mechanisms. Twenty one sets of three rate equations were retained and subjected to model discrimination and parameter estimation. The parameter estimates in the best model are statistically significant and thermodynamically consistent.
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Cited by
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LeValley, T. L., Richard, A. R., & Fan, M. (2014) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2014.08.041 · Cited by 643
A review of fuel cell systems for maritime applications
van Biert, L., Godjevac, M., Visser, K., & Aravind, P. V. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2016.07.007 · Cited by 624
Biomass Gasification in Supercritical Water
Antal, M. J., Allen, S. G., Schulman, D., Xu, X., & Divilio, R. J. (2000) · Industrial & Engineering Chemistry Research · doi:10.1021/ie0003436 · Cited by 610
Rostrup-Nielsen, J. R. (1993) · Catalysis Today · doi:10.1016/0920-5861(93)80059-a · Cited by 609
Gür, T. M. (2016) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2015.10.004 · Cited by 340
Metadata
- Authors
- Xu, J., & Froment, G. F.
- Venue
- AIChE Journal
- Publisher
- Wiley
- Published
- 1989-01
- Volume
- 35
- Issue
- 1
- Pages
- 88-96
- ISSN
- 0001-1541 (ISSN-L)
- 1547-5905
- OpenAlex
- W2105744137
- Cited by
- 2,359
- References
- 0
- FWCI
- 4.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xu, J., & Froment, G. F. (1989). Methane steam reforming, methanation and water‐gas shift: I. Intrinsic kinetics. AIChE Journal. https://doi.org/10.1002/aic.690350109
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