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Photoswitchable Supramolecular Hydrogels Formed by Cyclodextrins and Azobenzene Polymers
Abstract
Licht ins Dunkel: Ein supramolekulares Hydrogel wird durch das mit α-Cyclodextrinen versehene Glucan Curdlan (CD-CUR) und Azobenzol-modifizierte Polyacrylsäure gebildet (pAC12Azo). Der Sol-Gel-Übergang und die Morphologie des supramolekularen Hydrogels können durch Licht der entsprechenden Wellenlänge geschaltet werden, das die Bildung eines Einschlusskomplexes zwischen α-Cyclodextrinen und den Azobenzol-Einheiten steuert (siehe Bild).
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“The isomerization causes the angle change of the two isomers accompanied with the significant change in molecular length between 9.0Å (trans) and 5.5 Å (cis) [430,491].”
From A review of stimuli-responsive shape memory polymer composites (2013) · cites this paper as [491]
In the citing paper
“The isomerization causes the angle change of the two isomers accompanied with the significant change in molecular length between 9.0Å (trans) and 5.5 Å (cis) [430,491].”
From A review of stimuli-responsive shape memory polymer composites (2013) · cites this paper as [491]
Citations
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References 56 · Cited by 101
Research works printed but not linked: 4
- Balazs E. A., 1996, The structure of the Eye, 293
- 10.1021/ja048943 · DOI
- Amiel C., 2001, Macromolecular Assemblies Generated by Inclusion Complexes between Amphipathic Polymers and β‐Cyclodextrin Polymers in Aqueous Media in Stimuli‐Responsive Water Soluble and Amphiphilic Polymers, 58
- 10.1021/jp070798 · DOI
Metadata
- Authors
- Tamesue, S., Takashima, Y., Yamaguchi, H., Shinkai, S., & Harada, A.
- Affiliations
- The University of Osaka (JP)
- Institute of Systems, Information Technologies and Nanotechnologies (JP)
- Japan Science and Technology Agency (JP)
- Corresponding author
- Harada, Akira
- Venue
- Angewandte Chemie
- Publisher
- Wiley
- Published
- 2010-09-06
- Volume
- 122
- Issue
- 41
- Pages
- 7623-7626
- ISSN
- 0044-8249 (ISSN-L)
- 1521-3757
- OpenAlex
- W4237976776
- Cited by
- 101
- References
- 56
- Citations by year
- 2026: 4 · 2025: 2 · 2024: 2 · 2021: 4 · 2020: 6 · 2019: 7 · 2018: 7 · 2017: 7 · 2016: 9 · 2015: 13 · 2014: 12 · 2013: 12 · 2012: 8
- FWCI
- 3.69
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › Supramolecular Self-Assembly in Materials
- Physical Sciences › Chemistry › Organic Chemistry › Supramolecular Chemistry and Complexes
- Physical Sciences › Materials Science › Biomaterials › Hydrogels: synthesis, properties, applications
- Keywords
- supramolecular hydrogels, cyclodextrins, azobenzene polymers, curdlan, host-guest inclusion complexes, sol-gel transition, α-cyclodextrin
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