The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Abstract
Nanoparticles of cobalt phosphide, CoP, have been prepared and evaluated as electrocatalysts for the hydrogen evolution reaction (HER) under strongly acidic conditions (0.50 M H 2 SO 4, pH 0.3). Uniform, multi‐faceted CoP nanoparticles were synthesized by reacting Co nanoparticles with trioctylphosphine. Electrodes comprised of CoP nanoparticles on a Ti support (2 mg cm−2 mass loading) produced a cathodic current density of 20 mA cm−2 at an overpotential of −85 mV. The CoP/Ti electrodes were stable over 24 h of sustained hydrogen production in 0.50 M H 2 SO 4. The activity was essentially unchanged after 400 cyclic voltammetric sweeps, suggesting long‐term viability under operating conditions. CoP is therefore amongst the most active, acid‐stable, earth‐abundant HER electrocatalysts reported to date.
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Cites
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Self-citationRecent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
Kong, D., Cha, J. J., Wang, H., Lee, H. R., & Cui, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42413h · Cited by 1,031
Cao, B., Veith, G. M., Neuefeind, J. C., Adzic, R. R., & Khalifah, P. G. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4081056 · Cited by 998
Ni–Mo Nanopowders for Efficient Electrochemical Hydrogen Evolution
McKone, J. R., Sadtler, B. F., Werlang, C. A., Lewis, N. S., & Gray, H. B. (2013) · ACS Catalysis · doi:10.1021/cs300691m · Cited by 798
Self-citationDesulfurization Reactions on Ni2P(001) and α-Mo2C(001) Surfaces: Complex Role of P and C Sites
Liu, P., Rodriguez, J. A., Asakura, T., Gomes, J., & Nakamura, K. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp044301x · Cited by 305
Cited by
Atomic cobalt on nitrogen-doped graphene for hydrogen generation
Fei, H., Dong, J., Arellano-Jiménez, M. J., Ye, G., Dong Kim, N., Samuel, E. L. G., Peng, Z., Zhu, Z., Qin, F., Bao, J., et al. (2015) · Nature Communications · doi:10.1038/ncomms9668 · Cited by 1,621
Deng, J., Ren, P., Deng, D., & Bao, X. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201409524 · Cited by 1,314
Kibsgaard, J., & Jaramillo, T. F. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201408222 · Cited by 1,048
Jiang, P., Liu, Q., Liang, Y., Tian, J., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201406848 · Cited by 885
Is There Anything Better than Pt for HER?
Hansen, J. N., Prats, H., Toudahl, K. K., Mørch Secher, N., Chan, K., Kibsgaard, J., & Chorkendorff, I. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c00246 · Cited by 820
Metadata
- Authors
- Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E.
- Venue
- Angewandte Chemie
- Publisher
- Wiley
- Published
- 2014-04-11
- Volume
- 126
- Issue
- 21
- Pages
- 5531-5534
- ISSN
- 0044-8249 (ISSN-L)
- 1521-3757
- OpenAlex
- W4246087343
- Cited by
- 389
- References
- 8
- FWCI
- 23.25
- Type
- journal article
- Language
- de
- Open access
- closed
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- Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014). Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles. Angewandte Chemie. https://doi.org/10.1002/ange.201402646
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