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An Efficient Nanoscale Heterogeneous Catalyst for the Capture and Conversion of Carbon Dioxide at Ambient Pressure
Abstract
Silver nanoparticles were successfully supported on the zeolite‐type metal–organic framework MIL‐101 to yield Ag@MIL‐101 by a simple liquid impregnation method. For the first time, the conversion of terminal alkynes into propiolic acids with CO 2 was achieved by the use of the Ag@MIL‐101 catalysts. Owing to the excellent catalytic activity, the reaction proceeded at atmospheric pressure and low temperature (50 °C). The Ag@MIL‐101 porous material is of outstanding bifunctional character as it is capable of simultaneously capturing and converting CO 2 with low energy consumption and can be recovered easily by centrifugation.
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Citations
Cited by
Carbon capture and conversion using metal–organic frameworks and MOF-based materials
Ding, M., Flaig, R. W., Jiang, H.-L., & Yaghi, O. M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00829a · Cited by 2,616
Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis
Yang, Q., Xu, Q., & Jiang, H.-L. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00724d · Cited by 1,892
Highly Selective Conversion of Carbon Dioxide to Lower Olefins
Li, Z., Wang, J., Qu, Y., Liu, H., Tang, C., Miao, S., Feng, Z., An, H., & Li, C. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b03251 · Cited by 593
Liang, J., Huang, Y.-B., & Cao, R. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.11.013 · Cited by 444
Cui, W.-G., Zhang, G.-Y., Hu, T.-L., & Bu, X.-H. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.02.001 · Cited by 406
Metadata
- Authors
- Liu, X., Ma, J., Niu, Z., Yang, G., & Cheng, P.
- Venue
- Angewandte Chemie
- Publisher
- Wiley
- Published
- 2014-11-10
- Volume
- 127
- Issue
- 3
- Pages
- 1002-1005
- ISSN
- 0044-8249 (ISSN-L)
- 1521-3757
- OpenAlex
- W4234402712
- Cited by
- 250
- References
- 0
- FWCI
- 10.56
- Type
- journal article
- Language
- de
- Open access
- closed
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- Liu, X., Ma, J., Niu, Z., Yang, G., & Cheng, P. (2015). An Efficient Nanoscale Heterogeneous Catalyst for the Capture and Conversion of Carbon Dioxide at Ambient Pressure. Angewandte Chemie. https://doi.org/10.1002/ange.201409103
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