The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Heterolytic Fragmentation. A Class of Organic Reactions
Abstract
Heterolytic fragmentation is a widespread but neglected class of organic reactions. It involves the regulated cleavage of molecules containing certain combinations of atoms such as carbon, oxygen, nitrogen, sulfur, phosphorus, silicon, boron and halogens. Fragmentation reactions are useful in degradation and structure elucidation, some are also of preparative value. A knowledge of the structural and electronic requirements makes it possible to predict and influence the course of reactions. From a theoretical viewpoint the recognition of heterolytic fragmentation has lead to the classification and correlation of a large number of apparently diverse reactions. Selected cases are reviewed in this article.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
(1956) · Journal of the Franklin Institute · doi:10.1016/0016-0032(56)91284-4 · Cited by 1,949
Structure and Mechanism in Organic Chemistry
de Jong, G. (1954) · Chemical Engineering Science · doi:10.1016/0009-2509(54)85019-6 · Cited by 732
Une nouvelle méthode de synthèse peptidique
Boissonnas, R. A. (1951) · Helvetica Chimica Acta · doi:10.1002/hlca.19510340318 · Cited by 390
The Strecker Degradation of α-Amino Acids.
Schonberg, A., & Moubacher, R. (1952) · Chemical Reviews · doi:10.1021/cr60156a002 · Cited by 267
Über die Einwirkung von alkalischem Wasserstoffsuperoxyd auf ungesättigte Verbindungen
Weitz, E., & Scheffer, A. (1921) · Berichte der deutschen chemischen Gesellschaft (A and B Series) · doi:10.1002/cber.19210540922 · Cited by 241
Bartlett, M. F., Dickel, D. F., & Taylor, W. I. (1958) · Journal of the American Chemical Society · doi:10.1021/ja01534a036 · Cited by 131
Oxidation of α-Diketones andα-Keto-Acids by Hydrogen Peroxide
Bunton, C. A. (1949) · Nature · doi:10.1038/163444a0 · Cited by 95
Solvolyse von Carbonsäurederivaten, I. Reaktion von Carbonsäurehalogeniden mit Wasser und Aminen
Ugi, I., & Beck, F. (1961) · Chemische Berichte · doi:10.1002/cber.19610940722 · Cited by 49
The Action of Hydrogen Peroxide upon Simple Carbon Compounds. III. Glycolic Acid1
Fry, H. S., & Milstead, K. L. (1935) · Journal of the American Chemical Society · doi:10.1021/ja01314a068 · Cited by 6
Cited by
Reactions of oxyl radicals with DNA
Breen, A. P., & Murphy, J. A. (1995) · Free Radical Biology and Medicine · doi:10.1016/0891-5849(94)00209-3 · Cited by 1,038
Four‐membered cyclic peroxides: Carriers of chemical energy
Bastos, E. L., Farahani, P., Bechara, E. J. H., & Baader, W. J. (2017) · Journal of Physical Organic Chemistry · doi:10.1002/poc.3725 · Cited by 68
Metadata
- Authors
- Grob, C. A., & Schiess, P. W.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1967-01
- Volume
- 6
- Issue
- 1
- Pages
- 1-15
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W1964040328
- Cited by
- 354
- References
- 9
- FWCI
- 15.49
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Heterolytic Fragmentation. A Class of Organic Reactions. https://app.cochat.ai/papers/10.1002/anie.196700011
- The paper
- Grob, C. A., & Schiess, P. W. (1967). Heterolytic Fragmentation. A Class of Organic Reactions. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.196700011
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
