The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
The Solvent Dimethyl Sulfoxide
Abstract
The dipolar aprotic solvent dimethyl sulfoxide is liquid over a wide range of temperatures, is a strong electron donor, and has a high polarity. It is therefore an excellent and selective solvent for many organic and even polymeric compounds, and can enter into H‐bonding and dipole‐dipole association. The structure of dimethyl sulfoxide, with a “hard” oxygen atom and a “soft” sulfur atom, leads to good solvation of cations and poor solvation of anions. Mixtures of alkoxides with dimethyl sulfoxide are therefore among the most strongly basic systems in organic chemistry, and are excellently suited for the deprotonation of weakly acidic OH, NH, and CH bonds, for eliminations, and for the initiation of polymerizations.
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Cites
Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475
Corey, E. J., & Chaykovsky, M. (1965) · Journal of the American Chemical Society · doi:10.1021/ja01084a034 · Cited by 1,584
Basic principles of organic chemistry
Roberts, J. D., & Caserio, M. C. (1965) · Andalas University Repository (Andalas University) · Cited by 993
Structure and Mechanism in Organic Chemistry
de Jong, G. (1954) · Chemical Engineering Science · doi:10.1016/0009-2509(54)85019-6 · Cited by 732
The effects of solvation on the properties of anions in dipolar aprotic solvents
Parker, A. J. (1962) · Quarterly Reviews, Chemical Society · doi:10.1039/qr9621600163 · Cited by 598
Methylsulfinyl Carbanion (CH3-SO-CH2-). Formation and Applications to Organic Synthesis
Corey, E. J., & Chaykovsky, M. (1965) · Journal of the American Chemical Society · doi:10.1021/ja01084a033 · Cited by 531
A Survey of C-H Groups as Proton Donors in Hydrogen Bonding
Allerhand, A., & Schleyer, P. V. R. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00895a002 · Cited by 325
LeBel, R. G., & Goring, D. A. I. (1962) · Journal of Chemical & Engineering Data · doi:10.1021/je60012a032 · Cited by 305
Classification of Alcohols by Nuclear Magnetic Resonance Spectroscopy
Chapman, O. L., & King, R. (1964) · Journal of the American Chemical Society · doi:10.1021/ja01060a068 · Cited by 221
A theory of ion-solvent interaction
Buckingham, A. D. (1957) · Discussions of the Faraday Society · doi:10.1039/df9572400151 · Cited by 181
Metadata
- Authors
- Martin, D., Weise, A., & Niclas, H. ‐.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1967-04
- Volume
- 6
- Issue
- 4
- Pages
- 318-334
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2109582954
- Cited by
- 264
- References
- 23
- FWCI
- 12.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Martin, D., Weise, A., & Niclas, H. ‐. (1967). The Solvent Dimethyl Sulfoxide. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.196703181
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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