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Intramolecular Ene Reactions in Organic Synthesis
Abstract
Thermal cyclizations of appropriate dienes, enynes and related unsaturated systems, some of them carried out on an industrial scale, demonstrate increasingly the preparative power of the intramolecular ene reaction. A variety of substituted, fused and bridged ring systems, including natural products, are thus easily accessible in a regio‐ and stereo‐selective manner. Numerous examples are discussed systematically illustrating the possibilities, limitations, and common features of this cyclization reaction and its reverse ring‐opening process.
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Cited by
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Trost, B. (1991) · Science · doi:10.1126/science.1962206 · Cited by 4,798
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Tietze, L. F., & Beifuss, U. (1993) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199301313 · Cited by 1,379
Sedimentary 12- n -Propylcholestanes, Molecular Fossils Diagnostic of Marine Algae
Moldowan, J. M., Fago, F. J., Lee, C. Y., Jacobson, S. R., Watt, D. S., Slougui, N.-E., Jeganathan, A., & Young, D. C. (1990) · Science · doi:10.1126/science.247.4940.309 · Cited by 300
Ahuja, S., Raghunathan, R., Kumarasamy, E., Jockusch, S., & Sivaguru, J. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b08100 · Cited by 36
Metadata
- Authors
- Oppolzer, W., & Snieckus, V.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1978-07
- Volume
- 17
- Issue
- 7
- Pages
- 476-486
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W1989489348
- Cited by
- 405
- References
- 0
- FWCI
- 11.75
- Type
- journal article
- Language
- en
- Open access
- closed
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