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Cleavage of Water by Visible‐Light Irradiation of Colloidal CdS Solutions; Inhibition of Photocorrosion by RuO2
Abstract
The conversion of light into chemical fuels in photochemical devices equipped with semiconductor electrodes (e.g. of n‐CdS) is associated with a serious problem: “holes” produced in the valence band of the semidonductor upon irradiation migrate to the surface where photocorrosion occurs. In mi‐croheterogenous CdS systems this is remedied by a thin layer of RuO 2. A CdS sol prepared in the presence of maleic anhydride/styrene copolymer has now been loaded with RuO 2 and Pt; these CdS microelectrodes are surprisingly active catalysts for cleavage of H 2 O and H 2 S.
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Citations
Cited by
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Nanocomposite Materials for Optical Applications
Beecroft, L. L., & Ober, C. K. (1997) · Chemistry of Materials · doi:10.1021/cm960441a · Cited by 1,019
Hydrogen production from renewable sources: biomass and photocatalytic opportunities
Navarro, R. M., Sánchez-Sánchez, M. C., Alvarez-Galvan, M. C., Valle, F. D., & Fierro, J. L. G. (2009) · Energy Environ. Sci. · doi:10.1039/b808138g · Cited by 444
Metadata
- Authors
- Kalyanasundaram, K., Borgarello, E., Duonghong, D., & Grätzel, M.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1981-11
- Volume
- 20
- Issue
- 11
- Pages
- 987-988
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2172281837
- Cited by
- 158
- References
- 0
- FWCI
- 6.15
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Cleavage of Water by Visible‐Light Irradiation of Colloidal CdS Solutions; Inhibition of Photocorrosion by RuO2. https://app.cochat.ai/papers/10.1002/anie.198109871
- The paper
- Kalyanasundaram, K., Borgarello, E., Duonghong, D., & Grätzel, M. (1981). Cleavage of Water by Visible‐Light Irradiation of Colloidal CdS Solutions; Inhibition of Photocorrosion by RuO2. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.198109871
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
