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Hydrolysis Products of the Monomeric Amine Complex (C6H15N3)FeCl3: The Structure of the Octameric Iron(III) Cation of {[(C6H15N3)6Fe8(μ3‐O)2(μ2‐OH)12]Br7(H2O)}Br·8H2O
Abstract
An extraordinary cation with eight FeIII centres is contained in the title compound. It has been characterized X‐ray crystallographically as the first FeIII‐oligomer with more than three centres. Besides the strong bridging by oxo‐ and hydroxo‐groups the “hydrophobization” of the surface by the six amine ligands is worthy of note. In the crystal, seven of the eight Br⊖ ions and a H 2 O molecule are associated with the cation—it can thus be regarded as a bromide‐ion bearing complex monocation.
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(1999) · Choice Reviews Online · doi:10.5860/choice.37-0940 · Cited by 14,314
Cited by
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Molecule-based magnetic coolers
Zheng, Y.-Z., Zhou, G.-J., Zheng, Z., & Winpenny, R. E. P. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60337g · Cited by 578
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Wernsdorfer, W. (2001) · Advances in Chemical Physics · doi:10.1002/9780470141786.ch3 · Cited by 331
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Metadata
- Authors
- Weighardt, K., Pohl, K., Jibril, I., & Huttner, G.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1984-01
- Volume
- 23
- Issue
- 1
- Pages
- 77-78
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2102445384
- Cited by
- 301
- References
- 1
- FWCI
- 2.37
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Hydrolysis Products of the Monomeric Amine Complex (C6H15N3)FeCl3: The Structure of the Octameric Iron(III) Cation of {[(C6H15N3)6Fe8(μ3‐O)2(μ2‐OH)12]Br7(H2O)}Br·8H2O. https://app.cochat.ai/papers/10.1002/anie.198400771
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- Weighardt, K., Pohl, K., Jibril, I., & Huttner, G. (1984). Hydrolysis Products of the Monomeric Amine Complex (C6H15N3)FeCl3: The Structure of the Octameric Iron(III) Cation of {[(C6H15N3)6Fe8(μ3‐O)2(μ2‐OH)12]Br7(H2O)}Br·8H2O. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.198400771
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
