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Liquid Crystals: A Tool for Studies on Chirality
Abstract
Nematic liquid crystals are extremely sensitive to optically active molecules, which, at very low concentration, convert them into cholesteric liquid crystals. The purpose of this report is to review recent applications of liquid crystals to chirality studies. A brief discussion of the structure and properties of liquid crystals is followed by a survey of the methods currently being employed for the determination of the pitch and handedness of cholesteric liquid crystals. Of special interest in the formation of induced‐cholestric phases are the twisting powers of optically active compounds and the structural relationships between dopants and nematics. Liquid crystals can be used, inter alia, for the detection of small optical activities and for the determination of thermal racemization barriers and absolute configurations.
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Citations
Cited by
Noyori, R., & Kitamura, M. (1991) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199100491 · Cited by 1,214
Amplification of chirality in liquid crystals
Eelkema, R., & Feringa, B. L. (2006) · Organic & Biomolecular Chemistry · doi:10.1039/b608749c · Cited by 346
Absolute Asymmetric Synthesis under Physical Fields: Facts and Fictions
Avalos, M., Babiano, R., Cintas, P., Jiménez, J. L., Palacios, J. C., & Barron, L. D. (1998) · Chemical Reviews · doi:10.1021/cr970096o · Cited by 306
Control of dynamic helicity at the macro- and supramolecular level
Pijper, D., & Feringa, B. L. (2008) · Soft Matter · doi:10.1039/b801886c · Cited by 254
Metadata
- Authors
- Solladié, G., & Zimmermann, R. G.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1984-05
- Volume
- 23
- Issue
- 5
- Pages
- 348-362
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2080149146
- Cited by
- 308
- References
- 0
- FWCI
- 5.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- Solladié, G., & Zimmermann, R. G. (1984). Liquid Crystals: A Tool for Studies on Chirality. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.198403481
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