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Polymerization of Propene and Butene with a Chiral Zirconocene and Methylalumoxane as Cocatalyst
Abstract
A novel, soluble Ziegler‐Natta catalyst enables the preparation of isotactic polypropylene, which exhibits a higher degree of isotacticity than polymers that can be produced industrially with heterogeneous catalysts. Furthermore, isotactic polybutene can also be obtained with such a catalyst. The chiral, rigid zirconocene derivative 1 and methylalumoxane 2 are used for the catalysis. The polymerization activity is remarkably high. equation image
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Citations
Cited by
The development of functional group tolerant ROMP catalysts
Grubbs, R. H. (1994) · Journal of Macromolecular Science, Part A · doi:10.1080/10601329408545884 · Cited by 95
Champouret, Y., Hashmi, O. H., & Visseaux, M. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.03.015 · Cited by 80
Galimberti, M., Albizzati, E., Abis, L., & Bacchilega, G. (1991) · Die Makromolekulare Chemie · doi:10.1002/macp.1991.021921106 · Cited by 57
Production of Polyolefins by Metallocene Catalysts and Their Recycling by Pyrolysis
Kaminsky, W. (2016) · Macromolecular Symposia · doi:10.1002/masy.201500127 · Cited by 35
Self-citationSupervised machine learning for prediction of zirconocene-catalyzed α-olefin polymerization
Rizkin, B. A., & Hartman, R. L. (2019) · Chemical Engineering Science · doi:10.1016/j.ces.2019.115224 · Cited by 35
Metadata
- Authors
- Kaminsky, W., Külper, K., Brintzinger, H. H., & Wild, F. R. W. P.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1985-06
- Volume
- 24
- Issue
- 6
- Pages
- 507-508
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2162510578
- Cited by
- 896
- References
- 0
- FWCI
- 7.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kaminsky, W., Külper, K., Brintzinger, H. H., & Wild, F. R. W. P. (1985). Polymerization of Propene and Butene with a Chiral Zirconocene and Methylalumoxane as Cocatalyst. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.198505071
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