Student or educator? Sign up with your school email and get 6 months of Pro free.
Cited by 244

The DOI matches its Crossref record.

Methyltrioxorhenium(VII) as Catalyst for Epoxidations: Structure of the Active Species and Mechanism of Catalysis

Herrmann, Wolfgang A., Fischer, Richard W., Scherer, Wolfgang, Rauch, Monika U.·1993·Angewandte Chemie International Edition in English

Abstract

Explosive in the solid state, the bis(η2-peroxo) complex 1, which in solution is the active species in the epoxidation of olefins with [CH3ReO3], could be characterized by X-ray crystallography as the diglyme adduct 2. Under catalytic conditions (excess of H2O2), 1 is far more stable than in the free state.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1002/anie.199311571

Cites

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cited by

See all 244

Metadata

Authors
Herrmann, W. A., Fischer, R. W., Scherer, W., & Rauch, M. U.
Venue
Angewandte Chemie International Edition in English
Publisher
Wiley
Published
1993-08
Volume
32
Issue
8
Pages
1157-1160
ISSN
0570-0833 (ISSN-L)
OpenAlex
W2086648086
Cited by
244
References
0
FWCI
17.28
Type
journal article
Language
en
Open access
closed

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: Methyltrioxorhenium(VII) as Catalyst for Epoxidations: Structure of the Active Species and Mechanism of Catalysis. https://app.cochat.ai/papers/10.1002/anie.199311571
The paper
Herrmann, W. A., Fischer, R. W., Scherer, W., & Rauch, M. U. (1993). Methyltrioxorhenium(VII) as Catalyst for Epoxidations: Structure of the Active Species and Mechanism of Catalysis. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.199311571

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.