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A New Copper Selenide Cluster with PPh3 Ligands: [Cu146Se73(PPh3)30]
Abstract
The largest cluster characterized to date by a crystal structure analysis, [Cu 146 Se 73(PPh 3)30], forms in the reaction of CuCL with Se(SiMe 3)2 in the presence of PPh 3 in THF. The Cu‐Se core of this huge cluster is shielded perfectly by the PPh 3 ligands. In this way, a molecule with a diameter of about 40 Å is formed. As a result of a certain structural similarity with Cu 2 Se, the cluster could be considered as a Cu 2 Se particle protected by ligands.
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Cited by
Perspectives on the Physical Chemistry of Semiconductor Nanocrystals
Alivisatos, A. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9535506 · Cited by 3,595
Shuttles and Muscles: Linear Molecular Machines Based on Transition Metals
Collin, J.-P., Dietrich-Buchecker, C., Gaviña, P., Jimenez-Molero, M. C., & Sauvage, J.-P. (2001) · Accounts of Chemical Research · doi:10.1021/ar0001766 · Cited by 697
Metadata
- Authors
- Krautscheid, H., Fenske, D., Baum, G., & Semmelmann, M.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1993-09
- Volume
- 32
- Issue
- 9
- Pages
- 1303-1305
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2171802727
- Cited by
- 164
- References
- 0
- FWCI
- 8.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Krautscheid, H., Fenske, D., Baum, G., & Semmelmann, M. (1993). A New Copper Selenide Cluster with PPh3 Ligands: [Cu146Se73(PPh3)30]. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.199313031
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
