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Tetra‐p‐tolylporphyrin with an Inverted Pyrrole Ring: A Novel Isomer of Porphyrin
Abstract
Exchange of a β-methine unit for an N atom of a pyrrole ring of a porphyrin leads to a new type of porphyrin isomer, which is formed by condensation of pyrrole and P-tolylaldehyde. NiII ions are surprisingly coordinated by 1 as tetradentate ligand, that is through the three N atoms and the C atom of the inner cycle. The framework of the green metalloporhyrin is planar.
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Citations
Cited by
Porphyrin-based photosensitizers for use in photodynamic therapy
Sternberg, E. D., Dolphin, D., & Brückner, C. (1998) · Tetrahedron · doi:10.1016/s0040-4020(98)00015-5 · Cited by 987
Figure Eights, Möbius Bands, and More: Conformation and Aromaticity of Porphyrinoids
Stępień, M., Sprutta, N., & Latos‐Grażyński, L. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201003353 · Cited by 481
Self-citationmeso-Aryl-Substituted Expanded Porphyrins
Shin, J.-Y., Furuta, H., Yoza, K., Igarashi, S., & Osuka, A. (2001) · Journal of the American Chemical Society · doi:10.1021/ja0106624 · Cited by 349
Yamasumi, K., Notsuka, Y., Yamaoka, Y., Mori, S., Ishida, M., & Furuta, H. (2020) · Chemistry – A European Journal · doi:10.1002/chem.202002406 · Cited by 28
Cooling, N. A., Zhou, X., Sales, T. A., Sauer, S. E., Lind, S. J., Gordon, K. C., Jones, T. W., Burke, K. B., Dastoor, P. C., & Belcher, W. J. (2012) · Solar Energy Materials and Solar Cells · doi:10.1016/j.solmat.2011.10.036 · Cited by 18
Metadata
- Authors
- Chmielewski, P. J., Latos‐Grażyński, L., Rachlewicz, K., & Glowiak, T.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1994-04-18
- Volume
- 33
- Issue
- 7
- Pages
- 779-781
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2065569056
- Cited by
- 641
- References
- 0
- FWCI
- 15.11
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Chmielewski, P. J., Latos‐Grażyński, L., Rachlewicz, K., & Glowiak, T. (1994). Tetra‐p‐tolylporphyrin with an Inverted Pyrrole Ring: A Novel Isomer of Porphyrin. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.199407791
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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