The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Aromaticity and Antiaromaticity in Five‐Membered C4H4X Ring Systems: “Classical” and “Magnetic” Concepts May Not Be “Orthogonal”
Abstract
Energetic, geometric, and magnetic criteria yield quantitatively the same order of aromaticity (antiaromaticity) for the five-membered ring systems 1: the aromatic 6π electron systems are stabilized, their bond lengths are equalized, and the magnetic susceptibility exaltations are diamagnetic. In contrast, the antiaromatic 4π electron systems are destabilized, double bonds are localized, and susceptibility exaltations are paramagnetic.
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Cites
Comprehensive Heterocyclic Chemistry
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Theory of Magnetic Susceptibilities and NMR Chemical Shifts in Terms of Localized Quantities
Kutzelnigg, W. (1980) · Israel Journal of Chemistry · doi:10.1002/ijch.198000020 · Cited by 689
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Kutzelnigg, W., Fleischer, U., & Schindler, M. (1990) · NMR Basic Principles and Progress · doi:10.1007/978-3-642-75932-1_3 · Cited by 611
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Katritzky, A. R., Barczynski, P., Musumarra, G., Pisano, D., & Szafran, M. (1989) · Journal of the American Chemical Society · doi:10.1021/ja00183a002 · Cited by 461
Diamagnetic susceptibility exaltation in hydrocarbons
Dauben, H. J., Wilson, J. D., & Laity, J. L. (1969) · Journal of the American Chemical Society · doi:10.1021/ja01036a022 · Cited by 273
Diamagnetic susceptibility exaltation as a criterion of aromaticity
Dauben, H. J., Wilson, J. D., & Laity, J. L. (1968) · Journal of the American Chemical Society · doi:10.1021/ja01005a059 · Cited by 264
Fleischer, U., Kutzelnigg, W., Lazzeretti, P., & Muehlenkamp, V. (1994) · Journal of the American Chemical Society · doi:10.1021/ja00091a039 · Cited by 256
Cited by
Nucleus-Independent Chemical Shifts: A Simple and Efficient Aromaticity Probe
Schleyer, P. V. R., Maerker, C., Dransfeld, A., Jiao, H., & van Eikema Hommes, N. J. R. (1996) · Journal of the American Chemical Society · doi:10.1021/ja960582d · Cited by 6,210
Self-citationNucleus-Independent Chemical Shifts (NICS) as an Aromaticity Criterion
Chen, Z., Wannere, C. S., Corminboeuf, C., Puchta, R., & Schleyer, P. V. R. (2005) · Chemical Reviews · doi:10.1021/cr030088+ · Cited by 3,847
Self-citationWhich NICS Aromaticity Index for Planar π Rings Is Best?
Fallah-Bagher-Shaidaei, H., Wannere, C. S., Corminboeuf, C., Puchta, R., & Schleyer, P. V. R. (2006) · Organic Letters · doi:10.1021/ol0529546 · Cited by 1,257
Self-citationA Hierarchy of Homodesmotic Reactions for Thermochemistry
Wheeler, S. E., Houk, K. N., Schleyer, P. V. R., & Allen, W. D. (2009) · Journal of the American Chemical Society · doi:10.1021/ja805843n · Cited by 607
Miar, M., Shiroudi, A., Pourshamsian, K., Oliaey, A. R., & Hatamjafari, F. (2021) · Journal of Chemical Research · doi:10.1177/1747519820932091 · Cited by 580
Metadata
- Authors
- von Ragué Schleyer, P., Jiao, H., Goldfuss, B., & Freeman, P. K.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1995-02-21
- Volume
- 34
- Issue
- 3
- Pages
- 337-340
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2040986227
- Cited by
- 543
- References
- 32
- FWCI
- 33.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- von Ragué Schleyer, P., Jiao, H., Goldfuss, B., & Freeman, P. K. (1995). Aromaticity and Antiaromaticity in Five‐Membered C4H4X Ring Systems: “Classical” and “Magnetic” Concepts May Not Be “Orthogonal”. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.199503371
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