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A Series of Well‐Defined Metathesis Catalysts–Synthesis of [RuCl2(CHR′)(PR3)2] and Its Reactions
Abstract
Substantially better initiators and therefore considerably more reactive than complexes of type A, the novel metathesis catalysts B are easily prepared by the reaction of [RuCl2(PPh3)3] with the appropriate diazoalkanes and subsequent phosphane exchange. While the PPh3 derivatives are excellent catalysts for living ROMP of norbornene, the complex with R = Cy, R′ = Ph is also a very efficient catalyst for the metathesis of acyclic alkenes.
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Metadata
- Authors
- Schwab, P., France, M. B., Ziller, J. W., & Grubbs, R. H.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1995-10-02
- Volume
- 34
- Issue
- 18
- Pages
- 2039-2041
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2119578867
- Cited by
- 1,493
- References
- 0
- FWCI
- 41.39
- Type
- journal article
- Language
- en
- Open access
- closed
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