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Recent Developments of Molecular Chemistry for Sol–Gel Processes
Abstract
This review focuses on some aspects of the chemistry involved in the preparation of oxides by sol–gel methods. This field is opening interesting possibilities for molecular chemistry and among those presented herein are: (1) the use of precursors containing functional groups for the preparation of solids with specific chemical reactivity; (2) the non‐hydrolytic gelation (NHG) route, a new general method for the synthesis of oxides that allows the use of oxygen donors (ethers, alcohols, alkoxides) other than water; the mechanism is based on oxygen–carbon bond cleavage; (3) organic–inorganic hybrid solids containing covalent bonds for which the chemical reactivity is used to demonstrate the presence of substructure in the globally amorphous solid; the substructure greatly depends on the geometry of the organic moiety.
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Cited by
Designed Hybrid Organic−Inorganic Nanocomposites from Functional Nanobuilding Blocks
Sanchez, C., Soler-Illia, G. J. D. A. A., Ribot, F., Lalot, T., Mayer, C. R., & Cabuil, V. (2001) · Chemistry of Materials · doi:10.1021/cm011061e · Cited by 1,240
Advances in Homogeneous and Heterogeneous Catalytic Asymmetric Epoxidation
Xia, Q.-H., Ge, H.-Q., Ye, C.-P., Liu, Z.-M., & Su, K.-X. (2005) · Chemical Reviews · doi:10.1021/cr0406458 · Cited by 983
[60]Fullerene chemistry for materials science applications
Prato, M. (1997) · Journal of Materials Chemistry · doi:10.1039/a700080d · Cited by 833
Nonaqueous sol–gel routes to metal oxide nanoparticles
Niederberger, M. (2007) · Accounts of Chemical Research · doi:10.1021/ar600035e · Cited by 761
Croissant, J. G., Fatieiev, Y., Almalik, A., & Khashab, N. M. (2018) · Advanced Healthcare Materials · doi:10.1002/adhm.201700831 · Cited by 594
Metadata
- Authors
- Corriu, R. J. P., & Leclercq, D.
- Venue
- Angewandte Chemie International Edition in English
- Publisher
- Wiley
- Published
- 1996-07
- Volume
- 35
- Issue
- 13-14
- Pages
- 1420-1436
- ISSN
- 0570-0833 (ISSN-L)
- OpenAlex
- W2115193825
- Cited by
- 518
- References
- 0
- FWCI
- 22.63
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Recent Developments of Molecular Chemistry for Sol–Gel Processes. https://app.cochat.ai/papers/10.1002/anie.199614201
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- Corriu, R. J. P., & Leclercq, D. (1996). Recent Developments of Molecular Chemistry for Sol–Gel Processes. Angewandte Chemie International Edition in English. https://doi.org/10.1002/anie.199614201
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