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Phospha‐Organic Chemistry: Panorama and Perspectives
Abstract
Since the beginning of the seventies, organophosphorus chemistry has been completely rejuvenated by the discovery of stable derivatives in which phosphorus has the coordination numbers one or two. The chemistry of these compounds mimics the chemistry of their all‐carbon analogues. In this Review article this analogy is discussed for the phosphorus counterparts of alkenes, alkynes, and carbenes. In each case, the synthesis, reactivity, and coordination modes are briefly examined. Some special electronic configurations are also discussed, which include one‐electron PP bonds, strained bonds, and aromatic systems. To conclude, some potential applications of this chemistry in the areas of molecular materials and homogeneous catalysis are presented.
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Cites
To What Extent Can Aromaticity Be Defined Uniquely?
Cyrañski, M. K., Krygowski, T. M., Katritzky, A. R., & Schleyer, P. V. R. (2002) · The Journal of Organic Chemistry · doi:10.1021/jo016255s · Cited by 727
Cited by
P4 Activation by Late-Transition Metal Complexes
Caporali, M., Gonsalvi, L., Rossin, A., & Peruzzini, M. (2010) · Chemical Reviews · doi:10.1021/cr900349u · Cited by 448
Metadata
- Authors
- Mathey, F.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2003-04-10
- Volume
- 42
- Issue
- 14
- Pages
- 1578-1604
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2137013960
- Cited by
- 613
- References
- 1
- FWCI
- 22.32
- Type
- journal article
- Language
- en
- Open access
- closed
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