The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Experimental Observation and Confirmation of Icosahedral W@Au12 and Mo@Au12 Molecules
Abstract
Yes, [email protected]12 is icosahedral! We provide experimental verification of the recently proposed new class of gold clusters. Anion photoelectron spectroscopy and relativistic density functional calculations were used to show that both [email protected]12 and [email protected]12 are highly stable icosahedral clusters with large HOMO–LUMO gaps. The HOMO and LUMO of the Ih [email protected]12 clusters, both of hg symmetry, are bonding and antibonding orbitals between the W(Mo) 5d(4d) and the Au 6s–5d hybrids oriented along the radial directions of the icosahedron, similar to the C 2s–2pz radial hybrids in C60.
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Cites
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Self-citation
Cited by
Nanoalloys: From Theory to Applications of Alloy Clusters and Nanoparticles
Ferrando, R., Jellinek, J., & Johnston, R. L. (2008) · Chemical Reviews · doi:10.1021/cr040090g · Cited by 3,690
Metadata
- Authors
- Li, X., Kiran, B., Li, J., Zhai, H., & Wang, L.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2002-12-12
- Volume
- 41
- Issue
- 24
- Pages
- 4786-4789
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2153748697
- Cited by
- 357
- References
- 11
- FWCI
- 13.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, X., Kiran, B., Li, J., Zhai, H., & Wang, L. (2002). Experimental Observation and Confirmation of Icosahedral W@Au12 and Mo@Au12 Molecules. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200290048
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
