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Metal Carboxylates with Open Architectures
Abstract
The field of inorganic open‐framework materials is dominated by aluminosilicates and phosphates. The metal carboxylates have emerged as an important family in the last few years. This family includes not only mono‐ and dicarboxylates of transition, rare‐earth, and main‐group metals, but also a variety of hybrid structures. Some of the carboxylates possess novel adsorption and magnetic properties. Dicarboxylates and related species provide an effective means of designing novel hybrid structures with porous and other properties. In some of these structures, the dicarboxylate acts as a linker between two inorganic units. Hybrid nanocomposites are also of particular note, for example, cadmium oxalate host lattices that can accommodate extended alkali‐metal halide structures. This Review discusses the synthesis, structure, and properties of various types of open‐framework metal carboxylates.
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Cited by
Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Dybtsev, D. N., Chun, H., & Kim, K. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460712 · Cited by 1,208
Zeolite-like metal–organic frameworks (ZMOFs): design, synthesis, and properties
Eddaoudi, M., Sava, D. F., Eubank, J. F., Adil, K., & Guillerm, V. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00230j · Cited by 773
Tan, J. C., & Cheetham, A. K. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00163e · Cited by 762
Li, Z.-Q., Qiu, L.-G., Xu, T., Wu, Y., Wang, W., Wu, Z.-Y., & Jiang, X. (2009) · Materials Letters · doi:10.1016/j.matlet.2008.09.010 · Cited by 448
Metadata
- Authors
- Rao, C. N. R., Natarajan, S., & Vaidhyanathan, R.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2004-03-09
- Volume
- 43
- Issue
- 12
- Pages
- 1466-1496
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2000929824
- Cited by
- 1,935
- References
- 0
- FWCI
- 105.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Rao, C. N. R., Natarajan, S., & Vaidhyanathan, R. (2004). Metal Carboxylates with Open Architectures. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200300588
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