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Bioinspired Molecular Design of Light‐Harvesting Multiporphyrin Arrays
Abstract
Recent progress in fundamental studies on multiporphyrin arrays has provided structural parameters for the molecular design of artificial light‐harvesting antennae which mimic the wheel‐like antenna complexes of photosynthetic purple bacteria. Covalent and noncovalent approaches have been employed for the construction of artificial light‐harvesting multiporphyrin arrays. Such arrays are categorized into ring‐shaped, windmill‐shaped, star‐shaped, and dendritic architectures. In particular, dendritic multiporphyrin arrays have been proven to be promising candidates for both providing a large absorption cross‐section and enabling the vectorial transfer of energy over a long distance to a designated point. Such molecular and supramolecular systems are also expected to be potent components for molecular electronics and photonic devices.
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Cited by
Efficient Light Harvesting by Using Green Zn-Porphyrin-Sensitized Nanocrystalline TiO2 Films
Wang, Q., Campbell, W. M., Bonfantani, E. E., Jolley, K. W., Officer, D. L., Walsh, P. J., Gordon, K., Humphry-Baker, R., Nazeeruddin, M. K., & Grätzel, M. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp052877w · Cited by 438
Giant Multiporphyrin Arrays as Artificial Light-Harvesting Antennas
Imahori, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp038036b · Cited by 353
Towards Solar Fuels from Water and CO2
Centi, G., & Perathoner, S. (2010) · ChemSusChem · doi:10.1002/cssc.200900289 · Cited by 295
Single-Molecule Fluorescence Spectroscopy of Photosynthetic Systems
Kondo, T., Chen, W. J., & Schlau-Cohen, G. S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00195 · Cited by 120
Metadata
- Authors
- Choi, M., Yamazaki, T., Yamazaki, I., & Aida, T.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2003-12-19
- Volume
- 43
- Issue
- 2
- Pages
- 150-158
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2033020745
- Cited by
- 412
- References
- 0
- FWCI
- 15.47
- Type
- journal article
- Language
- en
- Open access
- closed
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- Choi, M., Yamazaki, T., Yamazaki, I., & Aida, T. (2004). Bioinspired Molecular Design of Light‐Harvesting Multiporphyrin Arrays. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200301665
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