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Multimetallic Cooperative Activation of N2
Abstract
The impressive number of breakthroughs reported in recent years in the field of dinitrogen activation reiterates the great interest that is still attracted by this molecule as a target for molecular activation studies. In spite of the fact that the discovery of dinitrogen fixation is rapidly approaching its 40th birthday, a thorough understanding of the factors that determine either fixation or activation is yet to be achieved. Nevertheless, substantial progress has recently been made. The aim of this article is to review some of the most recent literature and to assess the necessity of multimetallic attack to dinitrogen as a prerequisite towards further cleavage and functionalization.
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Cited by
Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store
Kitano, M., Inoue, Y., Yamazaki, Y., Hayashi, F., Kanbara, S., Matsuishi, S., Yokoyama, T., Kim, S.-W., Hara, M., & Hosono, H. (2012) · Nature Chemistry · doi:10.1038/nchem.1476 · Cited by 1,529
Arashiba, K., Miyake, Y., & Nishibayashi, Y. (2011) · Nature Chemistry · doi:10.1038/nchem.906 · Cited by 745
Ternary intermetallic LaCoSi as a catalyst for N2 activation
Gong, Y., Wu, J., Kitano, M., Wang, J., Ye, T.-N., Li, J., Kobayashi, Y., Kishida, K., Abe, H., Niwa, Y., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0022-0 · Cited by 319
Nitrogen reduction and functionalization by a multimetallic uranium nitride complex
Falcone, M., Chatelain, L., Scopelliti, R., Živković, I., & Mazzanti, M. (2017) · Nature · doi:10.1038/nature23279 · Cited by 317
Titanium-Based Hydrides as Heterogeneous Catalysts for Ammonia Synthesis
Kobayashi, Y., Tang, Y., Kageyama, T., Yamashita, H., Masuda, N., Hosokawa, S., & Kageyama, H. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b08891 · Cited by 282
Metadata
- Authors
- Gambarotta, S., & Scott, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2004-10-05
- Volume
- 43
- Issue
- 40
- Pages
- 5298-5308
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2139490622
- Cited by
- 322
- References
- 0
- FWCI
- 6.78
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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