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Efficient Methano[70]fullerene/MDMO‐PPV Bulk Heterojunction Photovoltaic Cells
Abstract
Owing to their increased absorption of light in the visible region, [70]fullerene derivatives provide a high photocurrent when incorporated as the electron acceptor in thin-film polymer photovoltaic cells. An incident-photon-to-current efficiency of 66 % is obtained when [70]PCBM (see picture) is used in combination with a poly(p-phenylene vinylene). These high currents originate from an ultrafast charge transfer that occurs upon photoexcitation of either the fullerene or the polymer.
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Citations
Cited by
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Günes, S., Neugebauer, H., & Sariciftci, N. S. (2007) · Chemical Reviews · doi:10.1021/cr050149z · Cited by 6,279
Bulk heterojunction solar cells with internal quantum efficiency approaching 100%
Park, S. H., Roy, A., Beaupré, S., Cho, S., Coates, N., Moon, J. S., Moses, D., Leclerc, M., Lee, K., & Heeger, A. J. (2009) · Nature Photonics · doi:10.1038/nphoton.2009.69 · Cited by 4,073
A polymer tandem solar cell with 10.6% power conversion efficiency
You, J., Dou, L., Yoshimura, K., Kato, T., Ohya, K., Moriarty, T., Emery, K., Chen, C.-C., Gao, J., Li, G., et al. (2013) · Nature Communications · doi:10.1038/ncomms2411 · Cited by 2,778
Small Molecule Organic Semiconductors on the Move: Promises for Future Solar Energy Technology
Mishra, A., & Bäuerle, P. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201102326 · Cited by 1,816
Small molecule semiconductors for high-efficiency organic photovoltaics
Lin, Y., Li, Y., & Zhan, X. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15313k · Cited by 1,751
Metadata
- Authors
- Wienk, M. M., Kroon, J. M., Verhees, W. J. H., Knol, J., Hummelen, J. C., van Hal, P. A., & Janssen, R. A. J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2003-07-24
- Volume
- 42
- Issue
- 29
- Pages
- 3371-3375
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2170456537
- Cited by
- 1,185
- References
- 0
- FWCI
- 42.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wienk, M. M., Kroon, J. M., Verhees, W. J. H., Knol, J., Hummelen, J. C., van Hal, P. A., & Janssen, R. A. J. (2003). Efficient Methano[70]fullerene/MDMO‐PPV Bulk Heterojunction Photovoltaic Cells. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200351647
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