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Characterization of a Dinuclear Mn V O Complex and Its Efficient Evolution of O 2 in the Presence of Water

Shimazaki, Yuichi, Nagano, Taro, Takesue, Hironori, Ye, Bao‐Hui, Tani, Fumito, Naruta, Yoshinori·2004·Angewandte Chemie International Edition

Abstract

A high valent MnVO porphyrin dimer is prepared by peracid oxidation of an MnIII dimer under basic conditions at room temperature (see scheme; mCPBA=m-chloroperbenzoic acid). The addition of an acid to a solution of the MnVO complex results in quantitative dioxygen evolution. Water and/or hydroxide ions are the sources of both the oxo ligand and the evolved dioxygen.

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Metadata

Authors
Shimazaki, Y., Nagano, T., Takesue, H., Ye, B., Tani, F., & Naruta, Y.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2003-12-17
Volume
43
Issue
1
Pages
98-100
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2133416961
Cited by
274
References
0
FWCI
5.98
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Characterization of a Dinuclear Mn V O Complex and Its Efficient Evolution of O 2 in the Presence of Water. https://app.cochat.ai/papers/10.1002/anie.200352564
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Shimazaki, Y., Nagano, T., Takesue, H., Ye, B., Tani, F., & Naruta, Y. (2004). Characterization of a Dinuclear Mn V O Complex and Its Efficient Evolution of O 2 in the Presence of Water. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200352564

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