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Characterization of a Dinuclear Mn V O Complex and Its Efficient Evolution of O 2 in the Presence of Water
Abstract
A high valent MnVO porphyrin dimer is prepared by peracid oxidation of an MnIII dimer under basic conditions at room temperature (see scheme; mCPBA=m-chloroperbenzoic acid). The addition of an acid to a solution of the MnVO complex results in quantitative dioxygen evolution. Water and/or hydroxide ions are the sources of both the oxo ligand and the evolved dioxygen.
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Cited by
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Kärkäs, M. D., Verho, O., Johnston, E. V., & Åkermark, B. (2014) · Chemical Reviews · doi:10.1021/cr400572f · Cited by 1,376
Molecular Catalysts for Water Oxidation
Blakemore, J. D., Crabtree, R. H., & Brudvig, G. W. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00122 · Cited by 1,150
Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins
Huang, X., & Groves, J. T. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00373 · Cited by 1,037
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects
Savéant, J.-M. (2008) · Chemical Reviews · doi:10.1021/cr068079z · Cited by 978
Artificial photosynthesis: opportunities and challenges of molecular catalysts
Zhang, B., & Sun, L. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00897c · Cited by 954
Metadata
- Authors
- Shimazaki, Y., Nagano, T., Takesue, H., Ye, B., Tani, F., & Naruta, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2003-12-17
- Volume
- 43
- Issue
- 1
- Pages
- 98-100
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2133416961
- Cited by
- 274
- References
- 0
- FWCI
- 5.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shimazaki, Y., Nagano, T., Takesue, H., Ye, B., Tani, F., & Naruta, Y. (2004). Characterization of a Dinuclear Mn V O Complex and Its Efficient Evolution of O 2 in the Presence of Water. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200352564
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