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Asymmetric Catalytic Aza‐Henry Reactions Leading to 1,2‐Diamines and 1,2‐Diaminocarboxylic Acids
Abstract
In the wake of the aldol and Mannich reactions, textbook examples of asymmetric reactions, comes the aza-Henry reaction (aka nitro-Mannich reaction), which leads to 1,2-diamines or α,β-diaminocarboxylic acids (see scheme, PG=protecting group). Recent developments point to a bright future for this transformation.
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Citations
Cited by
Parmar, D., Sugiono, E., Raja, S., & Rueping, M. (2014) · Chemical Reviews · doi:10.1021/cr5001496 · Cited by 2,118
Kobayashi, S., Mori, Y., Fossey, J. S., & Salter, M. M. (2011) · Chemical Reviews · doi:10.1021/cr100204f · Cited by 988
Chiral Proton Catalysis: A Catalytic Enantioselective Direct Aza-Henry Reaction
Nugent, B. M., Yoder, R. A., & Johnston, J. N. (2004) · Journal of the American Chemical Society · doi:10.1021/ja031906i · Cited by 358
Enantioselective Nitroaldol Reaction of α-Ketoesters Catalyzed by Cinchona Alkaloids
Li, H., Wang, B., & Deng, L. (2006) · Journal of the American Chemical Society · doi:10.1021/ja057237l · Cited by 347
Umpolung reactivity in amide and peptide synthesis
Shen, B., Makley, D. M., & Johnston, J. N. (2010) · Nature · doi:10.1038/nature09125 · Cited by 318
Metadata
- Authors
- Westermann, B.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2003-01-13
- Volume
- 42
- Issue
- 2
- Pages
- 151-153
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2063493194
- Cited by
- 197
- References
- 0
- FWCI
- 8.22
- Type
- journal article
- Language
- en
- Open access
- closed
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- Westermann, B. (2003). Asymmetric Catalytic Aza‐Henry Reactions Leading to 1,2‐Diamines and 1,2‐Diaminocarboxylic Acids. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200390071
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