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The Topotactic Conversion of a Novel Layered Silicate into a New Framework Zeolite

Ikeda, Takuji, Akiyama, Yoshikatsu, Oumi, Yasunori, Kawai, Akiko, Mizukami, Fujio·2004·Angewandte Chemie International Edition

Abstract

High-density silicate sheets made up of five-membered rings with Me4NOH molecules and K+ ions in the porelike interlayer space: This is the structure of the silicate PLS-1. When PLS-1 (left picture) was heated above 673 K under vacuum, the novel zeolite CDS-1 (right picture) was obtained as the result of topotactic dehydration–condensation reactions. CDS-1 is a pure silicate and thermally stable, and should therefore find a range of industrial uses.

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Metadata

Authors
Ikeda, T., Akiyama, Y., Oumi, Y., Kawai, A., & Mizukami, F.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2004-09-16
Volume
43
Issue
37
Pages
4892-4896
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2135430611
Cited by
191
References
0
FWCI
6.45
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: The Topotactic Conversion of a Novel Layered Silicate into a New Framework Zeolite. https://app.cochat.ai/papers/10.1002/anie.200460168
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Ikeda, T., Akiyama, Y., Oumi, Y., Kawai, A., & Mizukami, F. (2004). The Topotactic Conversion of a Novel Layered Silicate into a New Framework Zeolite. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200460168

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.