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Three‐Dimensional Structure of Large‐Pore Mesoporous Cubic Ia$\bar 3$d Silica with Complementary Pores and Its Carbon Replica by Electron Crystallography
Abstract
A bicontinuous cubic structure was revealed by electron crystallography on a large-pore mesoporous silica with a cubic Iad symmetry synthesized by using a triblock copolymer as a structure-directing agent. Its reconstructed structure (picture, left) is composed of an enantiomeric pair of interwoven three-dimensional mesoporous networks. Ordered complementary pores form interconnections between the two main channel systems at a special flat point of the G-surface (right).
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Citations
Cited by
On the controllable soft-templating approach to mesoporous silicates
Wan, Y., & Zhao (2007) · Chemical Reviews · doi:10.1021/cr068020s · Cited by 2,371
Kim, T.-W., Kleitz, F., Paul, B., & Ryoo, R. (2005) · Journal of the American Chemical Society · doi:10.1021/ja042601m · Cited by 733
Self-citationHierarchically Structured Zeolites: From Design to Application
Chen, L.-H., Sun, M.-H., Wang, Z., Yang, W., Xie, Z., & Su, B.-L. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00016 · Cited by 724
Park, Y. K., Choi, S. B., Kim, H., Kim, K., Won, B., Choi, K., Choi, J., Ahn, W., Won, N., Kim, S., et al. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200702324 · Cited by 320
Metadata
- Authors
- Sakamoto, Y., Kim, T., Ryoo, R., & Terasaki, O.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2004-09-29
- Volume
- 43
- Issue
- 39
- Pages
- 5231-5234
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2142883365
- Cited by
- 182
- References
- 0
- FWCI
- 8.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sakamoto, Y., Kim, T., Ryoo, R., & Terasaki, O. (2004). Three‐Dimensional Structure of Large‐Pore Mesoporous Cubic Ia$\bar 3$d Silica with Complementary Pores and Its Carbon Replica by Electron Crystallography. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200460449
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