The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Cross‐Coupling of Alkyl Halides with Aryl Grignard Reagents Catalyzed by a Low‐Valent Iron Complex
Abstract
A striking reversal of the usual reactivity pattern of aryl Grignard reagents is observed for reactions in the presence of catalytic amounts of the “bare” ferrate complex [Li(tmeda)]2[Fe(C2H4)4] (1). Highly reduced iron–magnesium clusters may play a decisive role in the exceptionally facile and chemoselective cross-coupling reaction with alkyl halides (see scheme).
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Iron-Catalyzed Cross-Coupling Reactions
Fürstner, A., Leitner, A., Méndez, M., & Krause, H. (2002) · Journal of the American Chemical Society · doi:10.1021/ja027190t · Cited by 823
Self-citationIron-Catalyzed Cross-Coupling of Primary and Secondary Alkyl Halides with Aryl Grignard Reagents
Nakamura, M., Matsuo, K., Ito, S., et al. (2004) · Journal of the American Chemical Society · doi:10.1021/ja049744t · Cited by 524
Fürstner, A., & Leitner, A. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020215)41:4<609::aid-anie609>3.0.co;2-m · Cited by 432
Self-citationRoom-Temperature Alkyl−Alkyl Suzuki Cross-Coupling of Alkyl Bromides that Possess β Hydrogens
Netherton, M. R., Dai, C., Neuschütz, K., & Fu, G. C. (2001) · Journal of the American Chemical Society · doi:10.1021/ja011306o · Cited by 419
Highly Stereo- and Chemoselective Iron-Catalyzed Alkenylation of Organomagnesium Compounds
Cahiez, G., & Avedissian, H. (1998) · Synthesis · doi:10.1055/s-1998-2135 · Cited by 380
Scheiper, B., Bonnekessel, M., Krause, H., & Fürstner, A. (2004) · The Journal of Organic Chemistry · doi:10.1021/jo0498866 · Cited by 339
Self-citationIron-Catalyzed Grignard Cross-Coupling with Alkyl Halides Possessing β-Hydrogens
Nagano, T., & Hayashi, T. (2004) · Organic Letters · doi:10.1021/ol049779y · Cited by 295
Catalysis‐Based Total Synthesis of Latrunculin B
Fürstner, A., De Souza, D., Parra‐Rapado, L., & Jensen, J. T. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200352413 · Cited by 172
Self-citationIron-Catalyzed Cross-Coupling Reactions. A Scalable Synthesis of the Immunosuppressive Agent FTY720
Seidel, G., Laurich, D., & Fürstner, A. (2004) · The Journal of Organic Chemistry · doi:10.1021/jo049885d · Cited by 153
Self-citationTetrakis(ethylene)irondilithium and Bis(η4‐1,5‐cy‐clooctadiene)irondilithium
Jonas, K., Schieferstein, L., Krüger, C. R., et al. (1979) · Angewandte Chemie International Edition in English · doi:10.1002/anie.197905501 · Cited by 77
Cited by
The Promise and Challenge of Iron-Catalyzed Cross Coupling
Sherry, B. D., & Fürstner, A. (2008) · Accounts of Chemical Research · doi:10.1021/ar800039x · Cited by 1,235
Self-citationFürstner, A. (2016) · ACS Central Science · doi:10.1021/acscentsci.6b00272 · Cited by 746
Self-citationAdvances in Iron Catalyzed Cross Coupling Reactions
Fürstner, A., & Martin, R. (2005) · Chemistry Letters · doi:10.1246/cl.2005.624 · Cited by 472
Self-citationRiener, K., Haslinger, S., Raba, A., Högerl, M. P., Cokoja, M., Herrmann, W. A., & Kühn, F. E. (2014) · Chemical Reviews · doi:10.1021/cr4006439 · Cited by 411
Katalyse von Radikalreaktionen: Konzepte aus Sicht der Radikalchemie
Studer, A., & Curran, D. P. (2016) · Angewandte Chemie · doi:10.1002/ange.201505090 · Cited by 313
Metadata
- Authors
- Martin, R., & Fürstner, A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2004-07-20
- Volume
- 43
- Issue
- 30
- Pages
- 3955-3957
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2049151058
- Cited by
- 400
- References
- 12
- FWCI
- 13.35
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Cross‐Coupling of Alkyl Halides with Aryl Grignard Reagents Catalyzed by a Low‐Valent Iron Complex. https://app.cochat.ai/papers/10.1002/anie.200460504
- The paper
- Martin, R., & Fürstner, A. (2004). Cross‐Coupling of Alkyl Halides with Aryl Grignard Reagents Catalyzed by a Low‐Valent Iron Complex. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200460504
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
