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Unveiling Reliable Catalysts for the Asymmetric Nitroaldol (Henry) Reaction
Abstract
Conceptually different chiral catalysts ranging from polymetallic complexes to Lewis acids and organocatalysts have emerged for solving the long-standing problem of stereocontrol in the Henry reaction, a fundamental CC bond-forming process (see scheme). New catalyst systems with improved selectivity have increased the synthetic value of this reaction considerably.
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Citations
Cited by
Cupreines and Cupreidines: An Emerging Class of Bifunctional Cinchona Organocatalysts
Marcelli, T., van Maarseveen, J. H., & Hiemstra, H. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602318 · Cited by 353
Enantioselective Nitroaldol Reaction of α-Ketoesters Catalyzed by Cinchona Alkaloids
Li, H., Wang, B., & Deng, L. (2006) · Journal of the American Chemical Society · doi:10.1021/ja057237l · Cited by 347
Umpolung reactivity in amide and peptide synthesis
Shen, B., Makley, D. M., & Johnston, J. N. (2010) · Nature · doi:10.1038/nature09125 · Cited by 318
Recent advances in cooperative bimetallic asymmetric catalysis: dinuclear Schiff base complexes
Matsunaga, S., & Shibasaki, M. (2014) · Chem. Commun. · doi:10.1039/c3cc47587e · Cited by 263
Metadata
- Authors
- Palomo, C., Oiarbide, M., & Mielgo, A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2004-10-13
- Volume
- 43
- Issue
- 41
- Pages
- 5442-5444
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2160931427
- Cited by
- 297
- References
- 0
- FWCI
- 11.23
- Type
- journal article
- Language
- en
- Open access
- closed
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- Palomo, C., Oiarbide, M., & Mielgo, A. (2004). Unveiling Reliable Catalysts for the Asymmetric Nitroaldol (Henry) Reaction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200460506
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