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A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction
Abstract
A perfect combination: The association of a chromium(III) trimeric building unit and 1,3,5-benzenetricarboxylate led to the powdered solid MIL-100. Simulations provided a crystal structure solution, which matched the experimental powder XRD pattern. This unique simulation/diffraction combination allowed the structure determination of a giant-pore solid with a zeotype architecture, built up from hybrid supertetrahedra (see picture).
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Citations
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Synthesis and catalytic properties of MIL-100(Fe), an iron(iii) carboxylate with large pores
Horcajada, P., Surblé, S., Serre, C., Hong, D.-Y., Seo, Y.-K., Chang, J.-S., Grenèche, J.-M., Margiolaki, I., & Férey, G. (2007) · Chem. Commun. · doi:10.1039/b704325b · Cited by 1,538
Self-citationDevelopment and Evaluation of Porous Materials for Carbon Dioxide Separation and Capture
Bae, Y., & Snurr, R. Q. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201101891 · Cited by 1,208
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Zeolite-like metal–organic frameworks (ZMOFs): design, synthesis, and properties
Eddaoudi, M., Sava, D. F., Eubank, J. F., Adil, K., & Guillerm, V. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00230j · Cited by 773
Metadata
- Authors
- Férey, G., Serre, C., Mellot‐Draznieks, C., Millange, F., Surblé, S., Dutour, J., & Margiolaki, I.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2004-11-23
- Volume
- 43
- Issue
- 46
- Pages
- 6296-6301
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2125485387
- Cited by
- 976
- References
- 0
- FWCI
- 26.25
- Type
- journal article
- Language
- en
- Open access
- closed
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- Férey, G., Serre, C., Mellot‐Draznieks, C., Millange, F., Surblé, S., Dutour, J., & Margiolaki, I. (2004). A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200460592
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