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Cooperative Catalysis by General Acid and Base Bifunctionalized Mesoporous Silica Nanospheres
Abstract
A team effort: Mesoporous silica nanosphere (MSN) materials bifunctionalized with a general acid group and a base group in various relative concentrations are described and shown to function as cooperative catalytic systems. The turnover numbers observed indicate that the acid groups can activate substrates in cooperation with the base groups to catalyze reactions that involve carbonyl activation (see picture).
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Citations
Cited by
Design and fabrication of mesoporous heterogeneous basic catalysts
Sun, L.-B., Liu, X.-Q., & Zhou, H.-C. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00090d · Cited by 386
Multifunctional Heterogeneous Catalysts: SBA‐15‐Containing Primary Amines and Sulfonic Acids
Zeidan, R. K., Hwang, S., & Davis, M. E. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602243 · Cited by 316
Chitosan as a sustainable organocatalyst: A concise overview
El Kadib, A. (2015) · ChemSusChem · doi:10.1002/cssc.201402718 · Cited by 237
Metadata
- Authors
- Huh, S., Chen, H., Wiench, J. W., Pruski, M., & Lin, V. S. ‐.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2005-03-08
- Volume
- 44
- Issue
- 12
- Pages
- 1826-1830
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2112024575
- Cited by
- 363
- References
- 0
- FWCI
- 12.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Cooperative Catalysis by General Acid and Base Bifunctionalized Mesoporous Silica Nanospheres. https://app.cochat.ai/papers/10.1002/anie.200462424
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- Huh, S., Chen, H., Wiench, J. W., Pruski, M., & Lin, V. S. ‐. (2005). Cooperative Catalysis by General Acid and Base Bifunctionalized Mesoporous Silica Nanospheres. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200462424
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