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Cited by 274

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CO Oxidation Catalyzed by Supported Gold: Cooperation between Gold and Nanocrystalline Rare‐Earth Supports Forms Reactive Surface Superoxide and Peroxide Species

Guzman, Javier, Carrettin, Silvio, Fierro‐Gonzalez, Juan C., Hao, Yalin, Gates, Bruce C., Corma, Avelino·2005·Angewandte Chemie International Edition
DOI 10.1002/anie.200500659
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Abstract

Beneficial defects: Reactive η1-superoxide and peroxide species at one-electron defect sites are formed at the metal–support interface in gold nanoclusters on nanocrystalline CeO2−x. These intermediates oxidize CO adsorbed on gold to form CO2. The reactive oxygen species are formed on nanocrystalline CeO2−x (see picture) but not on conventional CeO2, and their formation is enhanced by the gold.

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Metadata

Authors
Guzman, J., Carrettin, S., Fierro‐Gonzalez, J. C., Hao, Y., Gates, B. C., & Corma, A.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2005-07-18
Volume
44
Issue
30
Pages
4778-4781
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
DOI
10.1002/anie.200500659
OpenAlex
W2095113246
Cited by
274
References
0
FWCI
13.91
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: CO Oxidation Catalyzed by Supported Gold: Cooperation between Gold and Nanocrystalline Rare‐Earth Supports Forms Reactive Surface Superoxide and Peroxide Species. https://app.cochat.ai/papers/10.1002/anie.200500659
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Guzman, J., Carrettin, S., Fierro‐Gonzalez, J. C., Hao, Y., Gates, B. C., & Corma, A. (2005). CO Oxidation Catalyzed by Supported Gold: Cooperation between Gold and Nanocrystalline Rare‐Earth Supports Forms Reactive Surface Superoxide and Peroxide Species. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200500659

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.