The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Reactions in Micellar Systems
Abstract
The notion of “green chemistry” has encouraged even synthetic organic chemists to include water as a solvent. Incredible selectivities and activities can be achieved through the addition of amphiphiles with a defined structure. The morphology of supramolecular assemblies or associates formed by surfactants vary according to the temperature and concentration. As a rule, reactions are typically conducted using simple spherical aggregates, that is, micelles in the nanometer range. The strong polarity gradient present between the hydrophilic surface and the hydrophobic core of the micelle means that both nonpolar and polar reagents can be solubilized. This solubilization results in reactants becoming more concentrated within the micelle than in the surrounding water phase and leads to an acceleration of the reaction and causes selective effects. The kinetic treatment of reactions in micellar systems can be accomplished by considering them as microheterogeneous two‐phase systems.
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Cites
Autocatalytic self-replicating micelles as models for prebiotic structures
Bachmann, P. A., Luisi, P. L., & Lang, J. (1992) · Nature · doi:10.1038/357057a0 · Cited by 494
Manabe, K., Iimura, S., Sun, X.-M., & Kobayashi, S. (2002) · Journal of the American Chemical Society · doi:10.1021/ja026241j · Cited by 401
Cited by
Nanoparticulate Functional Materials
Goesmann, H., & Feldmann, C. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200903053 · Cited by 733
Molecular reactions at aqueous interfaces
Ruiz-Lopez, M. F., Francisco, J. S., Martins-Costa, M. T. C., & Anglada, J. M. (2020) · Nature Reviews Chemistry · doi:10.1038/s41570-020-0203-2 · Cited by 411
Cao, Y., Hu, X.-Y., Li, Y., Zou, X., Xiong, S., Lin, C., Shen, Y.-Z., & Wang, L. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505344t · Cited by 339
Mimicking the Cell: Bio-Inspired Functions of Supramolecular Assemblies
Tu, Y., Peng, F., Adawy, A., Men, Y., Abdelmohsen, L. K. E. A., & Wilson, D. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00344 · Cited by 316
Fallah-Araghi, A., Meguellati, K., Baret, J.-C., Harrak, A. E., Mangeat, T., Karplus, M., Ladame, S., Marques, C. M., & Griffiths, A. D. (2014) · Physical Review Letters · doi:10.1103/physrevlett.112.028301 · Cited by 301
Metadata
- Authors
- Dwars, T., Paetzold, E., & Oehme, G.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2005-11-08
- Volume
- 44
- Issue
- 44
- Pages
- 7174-7199
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2117282375
- Cited by
- 860
- References
- 2
- FWCI
- 17.66
- Type
- journal article
- Language
- en
- Open access
- closed
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