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An In Situ High‐Temperature Single‐Crystal Investigation of a Dehydrated Metal–Organic Framework Compound and Field‐Induced Magnetization of One‐Dimensional Metal–Oxygen Chains
Abstract
The arrangement of the spins of adjacent helical cobalt–oxygen chains that form the backbone of the framework (see figure) of a microporous coordination polymer lead to metamagnetic behavior. When the polymer is heated, the metal center loses a coordinated water molecule and alters its coordination geometry from octahedral to square-pyramidal, although the framework remains stable.
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Cited by
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Kökçam-Demir, Ü., Goldman, A., Esrafili, L., Gharib, M., Morsali, A., Weingart, O., & Janiak, C. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00609e · Cited by 895
Yang, L., Qian, S., Wang, X., Cui, X., Chen, B., & Xing, H. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00756c · Cited by 746
He, Y., Krishna, R., & Chen, B. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22858k · Cited by 674
Metadata
- Authors
- Dietzel, P. D. C., Morita, Y., Blom, R., & Fjellvåg, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2005-09-30
- Volume
- 44
- Issue
- 39
- Pages
- 6354-6358
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2168204708
- Cited by
- 591
- References
- 0
- FWCI
- 6.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: An In Situ High‐Temperature Single‐Crystal Investigation of a Dehydrated Metal–Organic Framework Compound and Field‐Induced Magnetization of One‐Dimensional Metal–Oxygen Chains. https://app.cochat.ai/papers/10.1002/anie.200501508
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- Dietzel, P. D. C., Morita, Y., Blom, R., & Fjellvåg, H. (2005). An In Situ High‐Temperature Single‐Crystal Investigation of a Dehydrated Metal–Organic Framework Compound and Field‐Induced Magnetization of One‐Dimensional Metal–Oxygen Chains. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200501508
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